Tingjie You, Si-Hao Zeng, Jianqiang Fan, Liangliang Wu, Fangyuan Kang, Yungen Liu and Chi-Ming Che
Chem. Commun., 2021,57, 10711-10714
DOI:
10.1039/D1CC04573C,
Communication
Herein, we describe a soluble iron(II)-phthalocyanine, [FeII(tBu4Pc)(py)2] (Pc = phthalocyaninato(2–)), as an effective catalyst in intramolecular C(sp3)–H bond amination, with alkyl azides as the nitrogen source, to afford the amination products in moderate to excellent yields with a broad substrate scope.
