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DOI: 10.1039/A809275C (Paper) Reference Section for: Chem. Commun., 1999, 633-634

Highly electrophilic lanthanide complexes containing fluorinated amido ligands: multiple Ln···F interactions, agostic interactions and η6-arene coordination

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Damon R. Click, Brian L. Scott and John G. Watkin

Abstract

Highly fluorinated amido ligands have been employed as supporting ligands for homoleptic lanthanide complexes; X-ray diffraction studies reveal multiple Ln···F interactions and a rare example of an η6-bound toluene solvent molecule.

References

  1. J. D. Scollard, D. H. McConville, N. C. Payne and J. J. Vittal, Macromolecules, 1996, 29, 5241 CrossRef CAS; R. Baumann, W. M. Davis and R. R. Schrock, J. Am. Chem. Soc., 1997, 119, 3830 CrossRef CAS.
  2. A. R. Johnson, W. M. Davis, C. C. Cummins, S. Serron, S. P. Nolan, D. G. Musaev and K. Morokuma, J. Am. Chem. Soc., 1998, 120, 2071 CrossRef CAS.
  3. A. L. Odom, P. L. Arnold and C. C. Cummins, J. Am. Chem. Soc., 1998, 120, 5836 CrossRef CAS; P. Roussel and P. Scott, J. Am. Chem. Soc., 1998, 120, 1070 CrossRef CAS.
  4. C. Rosenberger, R. R. Schrock and W. M. Davis, Inorg. Chem., 1997, 36, 123 CrossRef CAS; H. Memmler, U. Kauper, L. H. Gade, I. J. Scowen and M. McPartlin, Chem. Commun., 1996, 1751 RSC.
  5. Review article: R. Anwander, Top. Curr. Chem., 1996, 179, 33 Search PubMed See also: (a) R. K. Minhas, Y. Ma, J-I. Song and S. Gambarotta, Inorg. Chem., 1996, 35, 1866 CrossRef CAS; (b) W. J. Evans, M. A. Ansari, J. W. Ziller and S. I. Khan, Inorg. Chem., 1996, 35, 5435 CrossRef CAS.
  6. H. Sasai, S. Arai and M. Shibasaki, J. Org. Chem., 1994, 59, 2661 CrossRef CAS.
  7. O. Just, A. C. Greenwald and W. S. Rees, Jr., Mater. Res. Soc. Symp. Proc., 1996, 415, 111 CAS.
  8. D. C. Bradley, J. S. Ghotra and F. A. Hart, J. Chem. Soc., Dalton Trans., 1973, 1021 RSC.
  9. Examples of M⋯F interactions: H. Memmler, K. Walsh, L. H. Gade and J. W. Lauher, Inorg. Chem., 1995, 34, 4062 Search PubMed; A. R. Siedle, R. A. Newmark, W. M. Lamanna and J. C. Huffman, Organometallics, 1993, 12, 1491 CrossRef CAS.
  10. C. A. Hunter, X-J. Lu, G. M. Kapteijn and G. van Koten, J. Chem. Soc., Faraday Trans., 1995, 91, 2009 RSC.
  11. H. Schumann, J. Winterfeld, E. C. E. Rosenthal, H. Hemling and L. Esser, Z. Anorg. Allg. Chem., 1995, 621, 122 CrossRef CAS.
  12. D. R. Click, B. L. Scott and J. G. Watkin, unpublished results.
  13. R. Koppang, Acta Chem. Scand., 1971, 25, 3067 CAS.
  14. G. B. Deacon and Q. Shen, J. Organomet. Chem., 1996, 511, 1 CrossRef CAS.
  15. See, for example: (a) F. A. Cotton and W. Schwotzer, J. Am. Chem. Soc., 1986, 108, 4657 CrossRef CAS; (b) H. Liang, Q. Shen, J. Guan and Y. Lin, J. Organomet. Chem., 1994, 474, 113 CrossRef CAS; (c) B. Fan, Q. Shen and Y. Lin, J. Organomet. Chem., 1989, 377, 51 CrossRef CAS.
  16. J. D. Scollard and D. H. McConville, J. Am. Chem. Soc., 1996, 118, 10 008 CrossRef CAS.
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