Issue 54, 2024

Synthesis and catalytic application of a donor-free bismuthenium cation

Abstract

Herein, we report the synthesis and catalytic application of a new N,N′-dineopentyl-1,2-phenylenediamine-based bismuthenium cation (3). 3 has been synthesized via the treatment of chlorobismuthane LBiCl [L = 1,2-C6H4{N(CH2tBu)}2] (2) with AgSbF6, and was further used as a robust catalyst for the cyanosilylation of ketones under mild reaction conditions. Experimental studies and DFT calculations were performed to understand the mechanistic pathway.

Graphical abstract: Synthesis and catalytic application of a donor-free bismuthenium cation

Supplementary files

Article information

Article type
Communication
Submitted
16 Ebr. 2024
Accepted
06 Mezh. 2024
First published
07 Mezh. 2024

Chem. Commun., 2024,60, 6877-6880

Synthesis and catalytic application of a donor-free bismuthenium cation

N. Sen, P. Sarkar, Y. Meena, S. Tothadi, S. K. Pati and S. Khan, Chem. Commun., 2024, 60, 6877 DOI: 10.1039/D4CC01805B

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