Issue 21, 2019

NOx anion recognition by bimetallic cryptates: selectivity for nitrite over nitrate

Abstract

Nitrate and nitrite anions have multifaceted impacts on the environment and human health. We herein report selective recognition of nitrite over nitrate anion inside the cavity of bimetallic azacryptates having p-xylyl spacers. This work reveals a number of binding interactions which play pivotal roles in nitrite anion recognition by rigid metal cryptates.

Graphical abstract: NOx− anion recognition by bimetallic cryptates: selectivity for nitrite over nitrate

Supplementary files

Article information

Article type
Communication
Submitted
18 Ker. 2018
Accepted
04 Cʼhwe. 2019
First published
04 Cʼhwe. 2019

Dalton Trans., 2019,48, 7085-7089

NOx anion recognition by bimetallic cryptates: selectivity for nitrite over nitrate

T. Chattopadhyay, A. B. S., S. Gupta, A. S., J. A. Bertke and S. Kundu, Dalton Trans., 2019, 48, 7085 DOI: 10.1039/C8DT04971H

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