Issue 34, 2017

Sequence-coded ATRP macroinitiators

Abstract

Sequence-coded oligourethanes were tested as macroinitiators for the atom transfer radical polymerization (ATRP) of styrene. These oligomers were synthesized by solid-phase orthogonal iterative chemistry and transformed into ATRP initiators using a three-step modification procedure. A controlled radical polymerization behavior was observed with these macroinitiators, thus opening interesting opportunies for the synthesis of macromolecular architectures containing sequence-defined segments.

Graphical abstract: Sequence-coded ATRP macroinitiators

Supplementary files

Article information

Article type
Communication
Submitted
23 Meur. 2017
Accepted
07 Ebr. 2017
First published
07 Ebr. 2017

Polym. Chem., 2017,8, 4988-4991

Sequence-coded ATRP macroinitiators

S. Telitel, B. É. Petit, S. Poyer, L. Charles and J. Lutz, Polym. Chem., 2017, 8, 4988 DOI: 10.1039/C7PY00496F

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