Issue 9, 2017
From the journal:

Green Chemistry

Metal-free intramolecular amino-acyloxylation of 2-aminostyrene with carboxylic acid for the synthesis of 3-acyloxyl indolines in water†

Liyan Liua  and  Zhiyong Wang ORCID logo *a  

* Corresponding authors

a Hefei National Laboratory for Physical Sciences at Microscale, CAS Key Laboratory of Soft Matter Chemistry and Department of Chemistry & Collaborative Innovation Center of Suzhou Nano Science and Technology, University of Science and Technology of China, Hefei, P. R. China
E-mail: zwang3@ustc.edu.cn
Fax: (+86) 551-360-3185

Abstract

A metal-free amino-acyloxylation of 2-aminostyrene was developed for the synthesis of 3-acyloxyl indolines. In the presence of N,N,N-trimethyldodecan-1-aminium iodide and TBHP, the reaction can be carried out in water smoothly with various carboxylic acids. And for internal alkenes, a stereoselective product was formed.

Graphical abstract: Metal-free intramolecular amino-acyloxylation of 2-aminostyrene with carboxylic acid for the synthesis of 3-acyloxyl indolines in water

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Article information

DOI
https://doi.org/10.1039/C7GC00212B
Article type
Communication
Submitted
18 Gen. 2017
Accepted
15 Cʼhwe. 2017
First published
16 Cʼhwe. 2017

Green Chem., 2017,19, 2076-2079

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Metal-free intramolecular amino-acyloxylation of 2-aminostyrene with carboxylic acid for the synthesis of 3-acyloxyl indolines in water

L. Liu and Z. Wang, Green Chem., 2017, 19, 2076 DOI: 10.1039/C7GC00212B

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