Issue 15, 2017

Nitrile hydroboration reactions catalysed by simple nickel salts, bis(acetylacetonato)nickel(ii) and its derivatives

Abstract

Simple nickel salts, bis(acetylacetonato)nickel(II) and its derivatives, catalysed the hydroboration reactions of aryl and alkyl nitriles with catechol borane. The reaction smoothly proceeded for nitriles with various substituents to form the corresponding bis(boryl)amines in good to excellent yields.

Graphical abstract: Nitrile hydroboration reactions catalysed by simple nickel salts, bis(acetylacetonato)nickel(ii) and its derivatives

Supplementary files

Article information

Article type
Communication
Submitted
12 Mae 2017
Accepted
29 Mae 2017
First published
30 Mae 2017

Catal. Sci. Technol., 2017,7, 3196-3199

Nitrile hydroboration reactions catalysed by simple nickel salts, bis(acetylacetonato)nickel(II) and its derivatives

G. Nakamura, Y. Nakajima, K. Matsumoto, V. Srinivas and S. Shimada, Catal. Sci. Technol., 2017, 7, 3196 DOI: 10.1039/C7CY00944E

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