Issue 48, 2016

High proton conductivity in an unprecedented anionic metalloring organic framework (MROF) containing novel metalloring clusters with the largest diameter

Abstract

An attractive anionic metalloring organic framework (MROF-1) containing unprecedented sextuply interlocked nanocages made up of original metalloring clusters with the largest diameter of ca. 21 Å shows a high proton conductivity up to 1.72 × 10−2 S cm−1 at 70 °C and 97% RH, owing to plenty of counter cations (Me2NH2)+ located in the 1D channels.

Graphical abstract: High proton conductivity in an unprecedented anionic metalloring organic framework (MROF) containing novel metalloring clusters with the largest diameter

Supplementary files

Article information

Article type
Communication
Submitted
13 Gwen. 2016
Accepted
14 Du 2016
First published
15 Du 2016

J. Mater. Chem. A, 2016,4, 18742-18746

High proton conductivity in an unprecedented anionic metalloring organic framework (MROF) containing novel metalloring clusters with the largest diameter

Y. Han, Y. Ye, C. Tian, Z. Zhang, S. Du and S. Xiang, J. Mater. Chem. A, 2016, 4, 18742 DOI: 10.1039/C6TA07939C

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