Nano-scale characterization of binary self-assembled monolayers under an ambient condition with STM and TERS

Noriko N. Horimoto; Shigeru Tomizawa; Yasuhiko Fujita; Shinji Kajimoto; Hiroshi Fukumura

doi:10.1039/C4CC02754J

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Nano-scale characterization of binary self-assembled monolayers under an ambient condition with STM and TERS†

Noriko N. Horimoto,‡^a Shigeru Tomizawa,^a Yasuhiko Fujita,^a Shinji Kajimoto^a and Hiroshi Fukumura*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aramaki Aoba, Sendai 980-8578, Japan
E-mail: fukumura@m.tohoku.ac.jp
Fax: +81 22 795 6570
Tel: +81 22 795 6567

Abstract

Gold surfaces were modified by benzyl-mercaptan (BM) and then partly replaced with benzenethiol (BT), which formed binary self-assembled monolayers (SAM). Initially BT randomly replaced BM in the monolayer, but at long exchange times >15 nm radius domains were observed with specific relative composition of BT and BM.

This article is part of the themed collection: Scanning Probe Studies of Molecular Systems

Download options Please wait...

Supplementary files

Supplementary information PDF (807K)

Article information

DOI: https://doi.org/10.1039/C4CC02754J
Article type: Communication
Submitted: 14 Ebr. 2014
Accepted: 30 Mezh. 2014
First published: 04 Goue. 2014

Download Citation

Chem. Commun., 2014,50, 9862-9864

Author version available

Download author version (PDF)

Permissions

Request permissions

Nano-scale characterization of binary self-assembled monolayers under an ambient condition with STM and TERS

N. N. Horimoto, S. Tomizawa, Y. Fujita, S. Kajimoto and H. Fukumura, Chem. Commun., 2014, 50, 9862 DOI: 10.1039/C4CC02754J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications

Nano-scale characterization of binary self-assembled monolayers under an ambient condition with STM and TERS†

Abstract

Supplementary files

Article information

Download Citation

Author version available

Permissions

Nano-scale characterization of binary self-assembled monolayers under an ambient condition with STM and TERS

Social activity

Search articles by author

Spotlight

Advertisements