Using scanning tunnelling microscopy, we have visualized the segregation of carbon monoxide and hydrogen, the two reactants in Fischer–Tropsch synthesis, on cobalt nanoparticles at catalytically relevant coverages. Density functional theory was used to interrogate the relevant energetics.
E. A. Lewis, D. Le, A. D. Jewell, C. J. Murphy, T. S. Rahman and E. C. H. Sykes, Chem. Commun., 2014, 50, 6537 DOI: 10.1039/C4CC01680G
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