Issue 39, 2013
From the journal:

Chemical Communications

Synthesis, structure and reactivity of cyclopropenyl-1-ylidene stabilized S(ii), Se(ii) and Te(ii) mono- and dications†‡

Ágnes Kozma,a   Jekaterina Petuškova,a   Christian W. Lehmanna  and  Manuel Alcarazo*a  

* Corresponding authors

a Max Planck Institut für Kohlenforschung, 45470-Mülheim an der Ruhr, Germany
E-mail: alcarazo@mpi-muelheim.mpg.de
Fax: +49 208 3062994
Tel: +49 208 3062428

Abstract

The syntheses and structural characterization of carbene-stabilized chalcogen centred mono- and dications employing a reverse electron demand onio-substitutent transfer strategy are reported. The electronic structures of these compounds were determined by density functional calculations and their reactivity towards Pd(0) centres was evaluated.

Graphical abstract: Synthesis, structure and reactivity of cyclopropenyl-1-ylidene stabilized S(ii), Se(ii) and Te(ii) mono- and dications

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Article information

DOI
https://doi.org/10.1039/C2CC36225B
Article type
Communication
Submitted
27 Eost 2012
Accepted
12 Here 2012
First published
29 Here 2012

Chem. Commun., 2013,49, 4145-4147

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Synthesis, structure and reactivity of cyclopropenyl-1-ylidene stabilized S(II), Se(II) and Te(II) mono- and dications

Á. Kozma, J. Petuškova, C. W. Lehmann and M. Alcarazo, Chem. Commun., 2013, 49, 4145 DOI: 10.1039/C2CC36225B

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