Low temperature NMR studies indicate that the dicationic salts [Zr(η-C5H4CMe2C6H4Me-p)2]2+[MeB(C6F5)3]–2 and [Zr(η-C5H4CMe2Ph)2]2+ [MeB(C6F5)3]2– are formed when the neutral compounds [Zr(η-C5H4CMe2Ph)2Me2] and [Zr(η-C5H4CMe2C6H4Me-p)2Me2] and [Zr(η-C5H4CMe2Ph)2Me2] are treated with 2 equivalents of B(C6F5)3.
M. L. H. Green and J. Saßmannshausen, Chem. Commun., 1999, 115 DOI: 10.1039/A808197B
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