Issue 16, 2024

C8H6IN3O4: a birefringent crystal induced by uniformly aligned hybrid groups

Abstract

Herein, a novel optical crystal material, C8H6IN3O4, has been synthesized through rational design. Remarkably, C8H6IN3O4 showcases a large birefringence of 0.55@550 nm, surpassing those of commercially available birefringent materials. Theoretical calculations and analyses indicate that this phenomenon arises from the uniform alignment of π-conjugated [NO3] and [C8H6IN2O]+ groups.

Graphical abstract: C8H6IN3O4: a birefringent crystal induced by uniformly aligned hybrid groups

Supplementary files

Article information

Article type
Communication
Submitted
18 Ker. 2023
Accepted
24 Meur. 2024
First published
01 Ebr. 2024

J. Mater. Chem. C, 2024,12, 5696-5700

C8H6IN3O4: a birefringent crystal induced by uniformly aligned hybrid groups

Z. Chen, Q. Wu, J. Hong, G. Dong and L. Ma, J. Mater. Chem. C, 2024, 12, 5696 DOI: 10.1039/D3TC04666D

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