Issue 8, 2024

Overview of imidazole-based fluorescent materials with hybridized local and charge transfer and hot-exciton pathway characteristics in excited states

Abstract

Herein, we discuss an imidazole-based molecular framework, which can successfully transform triplet excitons present in high triplet levels into singlet states. We explain the working mechanisms of different methods for collecting triplet excitons, including hot excitons or HLCT states. After the development of an hot exciton material by Ma and Yang, many studies have demonstrated that the organic conjugated molecules having imidazole core have possibilities to show high efficiencies via hot exciton pathways. Finally, we provide a detailed investigation of recently published hot exciton luminogens based on imidazole molecular frameworks. This review provides an overview of the molecular structures, frontier molecular orbital information, and glass transition temperature of developed luminogens as well as the efficiency of organic light-emitting diodes (OLED) devices.

Graphical abstract: Overview of imidazole-based fluorescent materials with hybridized local and charge transfer and hot-exciton pathway characteristics in excited states

Article information

Article type
Review Article
Submitted
30 Goue. 2023
Accepted
08 Gen. 2024
First published
05 Cʼhwe. 2024

Soft Matter, 2024,20, 1669-1688

Overview of imidazole-based fluorescent materials with hybridized local and charge transfer and hot-exciton pathway characteristics in excited states

K. Kumar and D. Thakur, Soft Matter, 2024, 20, 1669 DOI: 10.1039/D3SM01005H

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