Issue 74, 2024
From the journal:

Chemical Communications

Photochemical α-amination of carbonyl groups with iodinanes†

Suyuan He,a   Boya Feng, ORCID logo a   Yiben Tang,a   Ruiping Chen,a   Yujing Guoa  and  Rene M. Koenigs ORCID logo *a  

* Corresponding authors

a RWTH Aachen University, Institute of Organic Chemistry, Landoltweg 1, 52074 Aachen, Germany
E-mail: rene.koenigs@rwth-aachen.de

Abstract

We report on a photochemical reaction of silyl enol ethers with iminoiodinanes. This aza Rubottom reaction provides a direct access towards α-amino carbonyl compounds under catalyst free reaction conditions with light as the sole source of energy. Control experiments suggest the participation of triplet nitrene intermediates.

Graphical abstract: Photochemical α-amination of carbonyl groups with iodinanes

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Article information

DOI
https://doi.org/10.1039/D4CC03564J
Article type
Communication
Submitted
17 Goue. 2024
Accepted
14 Eost 2024
First published
15 Eost 2024
This article is Open Access
Creative Commons BY license

Chem. Commun., 2024,60, 10128-10131

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Photochemical α-amination of carbonyl groups with iodinanes

S. He, B. Feng, Y. Tang, R. Chen, Y. Guo and R. M. Koenigs, Chem. Commun., 2024, 60, 10128 DOI: 10.1039/D4CC03564J

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