Issue 42, 2023

Recent advances in the synthesis of cyclic sulfinic acid derivatives (sultines and cyclic sulfinamides)

Abstract

The chemistry of cyclic sulfinic acid derivatives (sultines and cyclic sulfinamides) was underdeveloped for a long time due to their inaccessibility. Considering the importance of cyclic sulfinate esters and amides in the fields of chemistry, pharmaceutical science, and material science, synthesis strategies involving cyclic sulfinic acid derivatives have been paid more attention in recent years, and have been widely used in the synthesis of sulfur-containing compounds such as sulfoxides, sulfones, sulfinates and thioethers. Despite the impressive improvements that have been made in last twenty years with the new strategies, to date, no reviews have been published, to the best of our knowledge, dealing with the preparation of cyclic sulfinic acid derivatives. This review summarizes the latest advances in the development of new synthesis methods to access cyclic sulfinic acid derivatives in the last two decades. The synthetic strategies are reviewed by highlighting their product diversity, selectivity and applicability, and the mechanistic rationale is presented where possible. We wish to bring readers a comprehensive understanding of the state-of-play of cyclic sulfinic acid derivative formation and make a contribution to future research.

Graphical abstract: Recent advances in the synthesis of cyclic sulfinic acid derivatives (sultines and cyclic sulfinamides)

Article information

Article type
Feature Article
Submitted
13 Meur. 2023
Accepted
21 Ebr. 2023
First published
22 Ebr. 2023

Chem. Commun., 2023,59, 6272-6285

Recent advances in the synthesis of cyclic sulfinic acid derivatives (sultines and cyclic sulfinamides)

Y. Zhang, H. Li, X. Yang, P. Zhou and C. Shu, Chem. Commun., 2023, 59, 6272 DOI: 10.1039/D3CC01238G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements