Issue 21, 2022

Radical coupling reactions of hydrazines via photochemical and electrochemical strategies

Abstract

Hydrazines are versatile building blocks in organic synthesis. They are not only widely used for the preparation of numerous nitrogen-containing compounds, but also as coupling partners via denitrogenation in transition metal-catalysed coupling reactions. Recently, they have gained considerable attention as radical precursors for the formation of carbon–carbon and carbon–heteroatom bonds with or without release of nitrogen gas under the photochemical and electrochemical conditions. In this review, we will focus on the recent radical coupling reactions via photochemical and electrochemical strategies, and as well as discussion of their mechanisms.

Graphical abstract: Radical coupling reactions of hydrazines via photochemical and electrochemical strategies

Article information

Article type
Review Article
Submitted
23 Eost 2022
Accepted
28 Gwen. 2022
First published
30 Gwen. 2022

Org. Chem. Front., 2022,9, 6114-6128

Radical coupling reactions of hydrazines via photochemical and electrochemical strategies

Y. Kong, K. Wei and G. Yan, Org. Chem. Front., 2022, 9, 6114 DOI: 10.1039/D2QO01348G

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