Issue 88, 2022

Ligand-ligated Ni–Al bimetallic catalysis for C–H and C–C bond activation

Abstract

Compared with non-ligated Ni–Al bimetallic catalysis, bifunctional ligand-ligated Ni–Al bimetallic catalysis displays stronger synergism, not only affecting the electronic properties and steric hindrance of substrates, but also producing a directing effect for facile control of reactivity, site selectivity and enantioselectivity in the activation of C–H and C–C bonds. This review will give a brief summary of research advances in this field, highlighting the development of bifunctional ligands and their applications.

Graphical abstract: Ligand-ligated Ni–Al bimetallic catalysis for C–H and C–C bond activation

Article information

Article type
Feature Article
Submitted
31 Goue. 2022
Accepted
26 Gwen. 2022
First published
27 Gwen. 2022

Chem. Commun., 2022,58, 12260-12273

Ligand-ligated Ni–Al bimetallic catalysis for C–H and C–C bond activation

Y. Luan and M. Ye, Chem. Commun., 2022, 58, 12260 DOI: 10.1039/D2CC04274F

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