Issue 58, 2022

Catalytic machinery in motion: controlling catalysis via speed

Abstract

Three 3-component copper(I)-based slider-on-deck systems served as catalysts for a click reaction showing a higher catalytic activity with increasing sliding speed. Upon addition of brake stones, the motion of the resulting 4-component machinery was slowed and eventually stopped (on the NMR time scale) with the effect that catalysis was reduced or obstructed.

Graphical abstract: Catalytic machinery in motion: controlling catalysis via speed

Supplementary files

Article information

Article type
Communication
Submitted
05 Mae 2022
Accepted
20 Mezh. 2022
First published
21 Mezh. 2022
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2022,58, 8073-8076

Catalytic machinery in motion: controlling catalysis via speed

E. Elramadi, A. Ghosh, I. Valiyev, P. K. Biswas, T. Paululat and M. Schmittel, Chem. Commun., 2022, 58, 8073 DOI: 10.1039/D2CC02555H

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements