Issue 3, 2021

Between plasmonics and surface-enhanced resonant Raman spectroscopy: toward single-molecule strong coupling at a hotspot

Abstract

The purpose of this minireview is to build a bridge between two research fields: surface-enhanced resonant Raman spectroscopy (SERRS) under near-single-molecule conditions and the branch of plasmonics treating strong coupling between plasmons and molecular excitons. SERRS enables single-molecule spectroscopy owing to its significant enhancement at SERRS hotspots (HSs), localized at gaps or junctions between plasmonic nanoparticle aggregates. SERRS is SERS (surface enhanced Raman spectroscopy) under a resonant Raman excitation condition. The origin of the Raman enhancement in SERRS is electromagnetic coupling between plasmons and molecular excitons at HSs. It has been reported that the coupling energy at HSs reaches the strong coupling region, meaning that they are potential platforms for applications of single molecular excitons modified by strong coupling. In this review, we discuss recent progress related to electronic strong coupling in near-single-molecule SERRS: collective (e.g., vibrational) strong coupling is out of the scope of this minireview. First, we explain the relationship between the electromagnetic enhancement factor and coupling energy. Second, we introduce three theoretical methods for obtaining evidence of strong coupling at HSs. Third, we discuss a method for reproducing enhanced and modified molecular Raman and fluorescence spectra at HSs using the coupling energy. Finally, we propose the use of two experimental methods of absorption spectroscopy at HSs for modifying molecular electronic dynamics by strong coupling and comment on future applications of SERRS HSs to photophysics and photochemistry.

Graphical abstract: Between plasmonics and surface-enhanced resonant Raman spectroscopy: toward single-molecule strong coupling at a hotspot

Article information

Article type
Minireview
Submitted
14 Here 2020
Accepted
05 Gen. 2021
First published
06 Gen. 2021

Nanoscale, 2021,13, 1566-1580

Between plasmonics and surface-enhanced resonant Raman spectroscopy: toward single-molecule strong coupling at a hotspot

T. Itoh and Y. S. Yamamoto, Nanoscale, 2021, 13, 1566 DOI: 10.1039/D0NR07344J

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