Issue 33, 2021

Charge-transfer crystal with segregated packing structure constructed with hexaarylbenzene and tetracyanoquinodimethane

Abstract

Charge-transfer (CT) crystals bearing segregated domains between the electron donor and acceptor molecules are a promising platform for developing new organic functional solid-state materials. However, there is limited diversity in the segregated structures of CT crystals. Herein, we report a novel structure of a CT crystal using hexaarylbenzene (HAB) and tetracyanoquinodimethane (TCNQ) as the electron donors and acceptors, respectively. Single-crystal X-ray diffraction (XRD) studies revealed that hexapyridylbenzene and TCNQ form a segregated layer in crystalline media, and the CT feature of TCNQ was observed in terms of the observed chemical bond lengths in the crystal.

Graphical abstract: Charge-transfer crystal with segregated packing structure constructed with hexaarylbenzene and tetracyanoquinodimethane

Supplementary files

Article information

Article type
Communication
Submitted
03 Mezh. 2021
Accepted
02 Eost 2021
First published
03 Eost 2021

CrystEngComm, 2021,23, 5564-5568

Author version available

Charge-transfer crystal with segregated packing structure constructed with hexaarylbenzene and tetracyanoquinodimethane

R. Ando, M. Jin and H. Ito, CrystEngComm, 2021, 23, 5564 DOI: 10.1039/D1CE00726B

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