Issue 24, 2020

A molecular spin-crossover film allows for wavelength tuning of the resonance of a Fabry–Perot cavity

Abstract

We harness the remarkable refractive index switching (0.04 < Δn(λ) < 0.2) between the low-spin and high-spin states of the molecular spin-crossover (SCO) complex [Fe(HB(1,2,4-triazol-1-yl)3)2] to realize a wavelength-tunable Ag/SCO/Ag multilayer Fabry–Perot cavity. This tuneability is coupled with low absorption losses (k ≤ 10−4) between 350 and 1000 nm providing scope for reconfigurable and self-adaptive photonics applications in the visible spectral region.

Graphical abstract: A molecular spin-crossover film allows for wavelength tuning of the resonance of a Fabry–Perot cavity

Article information

Article type
Communication
Submitted
29 Ebr. 2020
Accepted
28 Mae 2020
First published
30 Mae 2020

J. Mater. Chem. C, 2020,8, 8007-8011

A molecular spin-crossover film allows for wavelength tuning of the resonance of a Fabry–Perot cavity

Y. Zhang, K. Ridier, V. Shalabaeva, I. Séguy, S. Pelloquin, H. Camon, S. Calvez, L. Routaboul, L. Salmon, G. Molnár and A. Bousseksou, J. Mater. Chem. C, 2020, 8, 8007 DOI: 10.1039/D0TC02094J

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