Issue 31, 2020

Rational design of dual-metal-site catalysts for electroreduction of carbon dioxide

Abstract

Electroreduction of carbon dioxide (CO2) to useful chemical fuels represents an efficient and green strategy for solving the existing energy and environmental problems of human society. Developing efficient and inexpensive electrocatalysts for the CO2 reduction reaction (CRR) has been a key scientific issue. Due to the robust scaling relationship that exists between CRR intermediates, it is difficult to improve the catalytic activity of commonly used transition metal catalysts. In this work, inspired by recent experimental progress in fabricating graphene-based dual-metal-site catalysts (DMSCs), we systematically studied the CRR activity of a series of DMSCs by means of density functional theory computations and micro-kinetics simulations. By using the adsorption strength of OH* and COOH* species as an indicator, three DMSCs, namely Cu/Mn, Ni/Mn and Ni/Fe, were identified as promising candidates after two-rounds of screening. Remarkably, it is found that the scaling relationship between the adsorption strength of COOH* and CO* species has been broken in these three DMSCs, leading to a superior CRR activity. Our work provides a useful guideline for further developing CRR electrocatalysts.

Graphical abstract: Rational design of dual-metal-site catalysts for electroreduction of carbon dioxide

Supplementary files

Article information

Article type
Paper
Submitted
02 Gen. 2020
Accepted
09 Meur. 2020
First published
09 Meur. 2020

J. Mater. Chem. A, 2020,8, 15809-15815

Rational design of dual-metal-site catalysts for electroreduction of carbon dioxide

G. Luo, Y. Jing and Y. Li, J. Mater. Chem. A, 2020, 8, 15809 DOI: 10.1039/D0TA00033G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements