Issue 11, 2019

Redox chemistry of an anionic dithiolene radical

Abstract

The redox chemistry of the first stable anionic dithiolene radical was investigated by both reactivity and cyclic voltammetry studies. While one-electron reduction of by Cp2Co or KC8 affords the corresponding dithiolate dimers 2 and 3, respectively, one-electron oxidation of by Ph3C+BF4 (or O2) conveniently gives 4, the neutral dithiolene dimer.

Graphical abstract: Redox chemistry of an anionic dithiolene radical

Supplementary files

Article information

Article type
Communication
Submitted
18 Ker. 2018
Accepted
07 Cʼhwe. 2019
First published
07 Cʼhwe. 2019

Dalton Trans., 2019,48, 3543-3546

Author version available

Redox chemistry of an anionic dithiolene radical

Y. Wang, Y. Xie, P. Wei, H. F. Schaefer and G. H. Robinson, Dalton Trans., 2019, 48, 3543 DOI: 10.1039/C8DT04989K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements