Transformation of the hydride-containing dinitrosyl iron complex [(NO)2Fe(η2-BH4)]− into [(NO)2Fe(η3-HCS2)]−via reaction with CS2

Huang-Chia Huang; Wei-Min Ching; Yu-Ting Tseng; Chien-Hong Chen; Tsai-Te Lu

doi:10.1039/C8DT04714F

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Transformation of the hydride-containing dinitrosyl iron complex [(NO)₂Fe(η²-BH₄)]⁻ into [(NO)₂Fe(η³-HCS₂)]⁻via reaction with CS₂†

Huang-Chia Huang,^a Wei-Min Ching,

^b Yu-Ting Tseng,^ac Chien-Hong Chen*^d and Tsai-Te Lu

*^ae

Author affiliations

* Corresponding authors

^a Department of Chemistry, Chung Yuan Christian University, Taoyuan, Taiwan

^b Instrumentation Center, National Taiwan Normal University, Taipei, Taiwan

^c Department of Chemistry, National Tsing Hua University, Hsinchu, Taiwan

^d Department of Medical Applied Chemistry, Chung Shan Medical University and Department of Medical Education, Chung Shan Medical University Hospital, Taichung 40201, Taiwan
E-mail: cchwind@csmu.edu.tw

^e Institute of Biomedical Engineering, National Tsing Hua University, Hsinchu, Taiwan
E-mail: ttlu@mx.nthu.edu.tw

Abstract

Reaction of compounds [(NO)₂Fe(TMEDA)] and [BH₄]⁻ affords the first hydride-containing dinitrosyl iron complex (DNIC) [(NO)₂Fe(η²-BH₄)]⁻ (2). Hydride-insertion reactivity of DNIC 2 promotes the reductive transformation of CS₂ into DNIC [(NO)₂Fe(η³-HCS₂)]⁻, the first DNIC featuring both linear/bent NO ligands and Fe 3d_z²-to-HCS₂ π* backbonding interaction.

This article is part of the themed collection: Bioinspired reactivity and coordination chemistry

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Article information

DOI: https://doi.org/10.1039/C8DT04714F
Article type: Communication
Submitted: 29 Du 2018
Accepted: 04 Gen. 2019
First published: 05 Gen. 2019

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Dalton Trans., 2019,48, 5897-5902

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Transformation of the hydride-containing dinitrosyl iron complex [(NO)₂Fe(η²-BH₄)]⁻ into [(NO)₂Fe(η³-HCS₂)]⁻via reaction with CS₂

H. Huang, W. Ching, Y. Tseng, C. Chen and T. Lu, Dalton Trans., 2019, 48, 5897 DOI: 10.1039/C8DT04714F

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Dalton Transactions