A tetranuclear CuII2DyIII2 coordination cluster as a Suzuki (C–C) coupling reaction promoter

Prashant Kumar; Kieran Griffiths; Christopher E. Anson; Annie K. Powell; George E. Kostakis

doi:10.1039/C8DT04371J

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A tetranuclear Cu ^II₂Dy ^III₂ coordination cluster as a Suzuki (C–C) coupling reaction promoter†

Prashant Kumar,^a Kieran Griffiths,^a Christopher E. Anson,

^b Annie K. Powell

*^bc and George E. Kostakis

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, School of Life Sciences, University of Sussex, Brighton BN19QJ, UK
E-mail: G.Kostakis@sussex.ac.uk

^b Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, 76131 Karlsruhe, Germany
E-mail: Annie.powell@kit.edu

^c Institute of Nanotechnology, Karlsruhe Institute of Technology, Postfach 3640, 76021 Karlsruhe, Germany

Abstract

The air-stable tetranuclear coordination cluster [Cu^II₂Dy^III₂L₄(NO₃)₂(CH₃CN)₂]·2(CH₃CN), which can be obtained in high yield, promotes the Suzuki coupling reaction of phenylboronic acid with substituted aryl halides under environmentally benign conditions.

This article is part of the themed collection: Challenges in organometallic & coordination chemistry: in celebration of Geoff Cloke’s 65th birthday

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Article information

DOI: https://doi.org/10.1039/C8DT04371J
Article type: Communication
Submitted: 02 Du 2018
Accepted: 15 Du 2018
First published: 15 Du 2018

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Dalton Trans., 2018,47, 17202-17205

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A tetranuclear Cu^II₂Dy^III₂ coordination cluster as a Suzuki (C–C) coupling reaction promoter

P. Kumar, K. Griffiths, C. E. Anson, A. K. Powell and G. E. Kostakis, Dalton Trans., 2018, 47, 17202 DOI: 10.1039/C8DT04371J

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Dalton Transactions