The “Wanderlust” of Me3Si groups in rare-earth triple-decker complexes: a combined experimental and computational study

Volker Lorenz; Phil Liebing; Adrien Bathelier; Felix Engelhardt; Laurent Maron; Liane Hilfert; Sabine Busse; Frank T. Edelmann

doi:10.1039/C8CC05317K

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The “Wanderlust” of Me₃Si groups in rare-earth triple-decker complexes: a combined experimental and computational study†‡

Volker Lorenz,^a Phil Liebing,

^b Adrien Bathelier,^c Felix Engelhardt,^a Laurent Maron,*^c Liane Hilfert,^a Sabine Busse^a and Frank T. Edelmann

*^a

Author affiliations

* Corresponding authors

^a Chemisches Institut der Otto-von-Guericke-Universität, 39106 Magdeburg, Germany
E-mail: frank.edelmann@ovgu.de

^b ETH Zürich, Laboratorium für Anorganische Chemie, Vladimir-Prelog-Weg 2, 8093 Zürich, Switzerland

^c Université de Toulouse, INSA, UPS, CNRS-UMR5215, LPCNO Avenue de Rangueil 135, 31077 Toulouse, France
E-mail: laurent.maron@irsamc.ups-tlse.fr

Abstract

The migration of Me₃Si groups (“Wanderlust”) in rare-earth triple-decker sandwich complexes of the type Ln₂(COT′′)₃ (COT′′ = bis(trimethylsilyl)cyclooctatetraenyl) has been elucidated by a combined experimental and computational study. For the first time, two isomers of a Ln₂(COT′′)₃ triple-decker have been isolated and characterized in the case of Y₂(COT′′)₃.

This article is part of the themed collection: New molecules and materials from the f-block

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Article information

DOI: https://doi.org/10.1039/C8CC05317K
Article type: Communication
Submitted: 02 Goue. 2018
Accepted: 20 Eost 2018
First published: 21 Eost 2018

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Chem. Commun., 2018,54, 10280-10283

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The “Wanderlust” of Me₃Si groups in rare-earth triple-decker complexes: a combined experimental and computational study

V. Lorenz, P. Liebing, A. Bathelier, F. Engelhardt, L. Maron, L. Hilfert, S. Busse and F. T. Edelmann, Chem. Commun., 2018, 54, 10280 DOI: 10.1039/C8CC05317K

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