Issue 7, 2014

Design of a new series of chiral phosphite–olefin ligands and their application in asymmetric catalysis

Abstract

A novel type of open-chain chiral chelating olefin bearing a simple monophosphite unit with a binaphthyl backbone was designed and synthesized, which could serve as an elegant chiral bidentate ligand in the rhodium-catalyzed asymmetric 1,2-additions of organoboron reagents to α-diketones and N-sulfonyl aldimines.

Graphical abstract: Design of a new series of chiral phosphite–olefin ligands and their application in asymmetric catalysis

Supplementary files

Article information

Article type
Research Article
Submitted
08 Mae 2014
Accepted
04 Mezh. 2014
First published
05 Mezh. 2014

Org. Chem. Front., 2014,1, 738-741

Design of a new series of chiral phosphite–olefin ligands and their application in asymmetric catalysis

Y. Yu and M. Xu, Org. Chem. Front., 2014, 1, 738 DOI: 10.1039/C4QO00135D

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