Issue 39, 2013

Formal γ-alkynylation of ketonesvia Pd-catalyzed C–C cleavage

Abstract

A formal γ-alkynylation of ketones via Pd-catalyzed C–C bond-cleavage is presented. The method allows for the coupling of tert-cyclobutanols and bromoacetylenes, giving access to versatile alkynes that are beyond reach otherwise.

Graphical abstract: Formal γ-alkynylation of ketones via Pd-catalyzed C–C cleavage

Supplementary files

Article information

Article type
Communication
Submitted
05 Here 2012
Accepted
29 Here 2012
First published
30 Here 2012

Chem. Commun., 2013,49, 4286-4288

Formal γ-alkynylation of ketones via Pd-catalyzed C–C cleavage

A. Ziadi, A. Correa and R. Martin, Chem. Commun., 2013, 49, 4286 DOI: 10.1039/C2CC37281A

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