Issue 39, 2013
From the journal:

Chemical Communications

Divergent reaction pathways of tris(oxazolinyl)borato zinc and magnesium silyl compounds†‡

Debabrata Mukherjee,a   Nicole L. Lampland,a   KaKing Yan,a   James F. Dunne,a   Arkady Ellerna  and  Aaron D. Sadow*a  

* Corresponding authors

a Department of Chemistry, Iowa State University, Ames, IA, USA
E-mail: sadow@iastate.edu
Fax: +1 515 2940105
Tel: +1 515 2948069

Abstract

Synthesis and reactivity of monomeric magnesium and zinc silyl compounds ToMM–Si(SiHMe2)3 and ToMM–Si(SiMe3)3 are described (ToM = tris(4,4-dimethyl-2-oxazolinyl)phenylborate). The magnesium compounds react slowly with water and air, while the zinc compounds are inert. With CO2, ToMMg–Si(SiHMe2)3 provides ToMMgO2CSi(SiHMe2)3 through CO2 insertion, whereas ToMZn–Si(SiHMe2)3 affords ToMZnOCHO.

Graphical abstract: Divergent reaction pathways of tris(oxazolinyl)borato zinc and magnesium silyl compounds

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Article information

DOI
https://doi.org/10.1039/C2CC36953B
Article type
Communication
Submitted
25 Gwen. 2012
Accepted
16 Du 2012
First published
28 Du 2012

Chem. Commun., 2013,49, 4334-4336

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Divergent reaction pathways of tris(oxazolinyl)borato zinc and magnesium silyl compounds

D. Mukherjee, N. L. Lampland, K. Yan, J. F. Dunne, A. Ellern and A. D. Sadow, Chem. Commun., 2013, 49, 4334 DOI: 10.1039/C2CC36953B

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