The first structurally authenticated zerovalent heteroarene complex of a lanthanide; synthesis and X-ray structure of bis(2,4,6-tri-tert-butyl- phosphorin)holmium(O)
Abstract
Holmium vapour reacts with 2,4,6-tri-tert-butylphosphorin to
afford the zerovalent
[Ho(η-PC
5
H
2
Bu
t
3
-2,4,6)
2
], the first structurally characterised complex of this
class.
- This article is part of the themed collection: Geoff Cloke at 65: a pioneer in organometallic chemistry
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