Issue 51, 2023

A molecular aluminium fulleride

Abstract

The reaction of alumylene [(Dippnacnac)Al] (1) with C60 fashions the first example of a structurally characterised aluminium-fulleride complex, [{(Dippnacnac)Al}3C60] (2), in which the Al centres are covalently bound to significantly elongated 6 : 6 bonds. Hydrolysis of 2 yields C60H6 and the reaction of 2 with [{Mesnacnac)Mg}2] cleaved off the Al fragments by affording the fulleride [{Mesnacnac)Mg}6C60].

Graphical abstract: A molecular aluminium fulleride

Supplementary files

Article information

Article type
Communication
Submitted
31 Meur. 2023
Accepted
31 Mae 2023
First published
06 Mezh. 2023

Chem. Commun., 2023,59, 7923-7926

A molecular aluminium fulleride

S. R. Lawrence, T. Rüffer, A. Stasch and R. Kretschmer, Chem. Commun., 2023, 59, 7923 DOI: 10.1039/D3CC01609A

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