Issue 21, 2019

One-dimensional magnetic chain composed of CuII and polychlorinated dipyridylphenylmethyl radical: temperature-dependent Jahn–Teller distortion correlated to π-conjugation and magnetic properties

Abstract

The one-dimensional coordination polymer composed of CuII and an organic radical bisPyTM displayed temperature dependent Jahn–Teller distortion, which is correlated to the π-conjugation mode at the ligand as well as the magnetic properties. The ferromangetic bisPyTM–CuII interaction was enhanced by the reorientation of the CuII dx2y2 orbital at low temperature.

Graphical abstract: One-dimensional magnetic chain composed of CuII and polychlorinated dipyridylphenylmethyl radical: temperature-dependent Jahn–Teller distortion correlated to π-conjugation and magnetic properties

Supplementary files

Article information

Article type
Communication
Submitted
24 Ker. 2018
Accepted
21 Gen. 2019
First published
25 Gen. 2019

Dalton Trans., 2019,48, 7090-7093

Author version available

One-dimensional magnetic chain composed of CuII and polychlorinated dipyridylphenylmethyl radical: temperature-dependent Jahn–Teller distortion correlated to π-conjugation and magnetic properties

S. Kimura, H. Uchida, T. Kusamoto and H. Nishihara, Dalton Trans., 2019, 48, 7090 DOI: 10.1039/C8DT05104F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements