Issue 15, 2018

Dehydrogenation of dimethylamine-borane mediated by Group 1 pincer complexes

Abstract

Group 1 salts containing carbazolido NNN pincer ligands are precatalysts for the dehydrogenation of Me2NH·BH3. NMR monitoring and DOSY studies show a heavy dependence on the metal and solvent, allowing in some cases selective formation of dehydrogenation products consistent with hydrogen liberation.

Graphical abstract: Dehydrogenation of dimethylamine-borane mediated by Group 1 pincer complexes

Supplementary files

Article information

Article type
Communication
Submitted
31 Here 2017
Accepted
04 Gen. 2018
First published
04 Gen. 2018

Chem. Commun., 2018,54, 1825-1828

Dehydrogenation of dimethylamine-borane mediated by Group 1 pincer complexes

R. Nolla-Saltiel, A. M. Geer, W. Lewis, A. J. Blake and D. L. Kays, Chem. Commun., 2018, 54, 1825 DOI: 10.1039/C7CC08385H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements