Reversible dinitrogen binding to [Cp′Fe(NHC)] associated with an N2-induced spin state change

Matthias Reiners; Dirk Baabe; Marc-Kevin Zaretzke; Matthias Freytag; Marc D. Walter

doi:10.1039/C7CC01535F

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Reversible dinitrogen binding to [Cp′Fe(NHC)] associated with an N₂-induced spin state change†

Matthias Reiners,^a Dirk Baabe,^a Marc-Kevin Zaretzke,^a Matthias Freytag^a and Marc D. Walter

*^a

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* Corresponding authors

^a Institut für Anorganische und Analytische Chemie, Technische Universität, Braunschweig, Hagenring 30, 38106 Braunschweig, Germany
E-mail: mwalter@tu-bs.de

Abstract

The 15-valence electron (VE), high-spin (S = 3/2) half-sandwich complex [Cp′Fe(IiPr₂Me₂)] (3; IiPr₂Me₂ = 1,3-di-iso-propyl-4,5-dimethylimidazol-2-yildene) reversibly coordinates N₂ to form the 17VE, low-spin (S = 1/2) compound [Cp′Fe(IiPr₂Me₂)(η¹-N₂)] (4).

This article is part of the themed collection: 2017 Emerging Investigators

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Article information

DOI: https://doi.org/10.1039/C7CC01535F
Article type: Communication
Submitted: 27 Cʼhwe. 2017
Accepted: 03 Ebr. 2017
First published: 10 Ebr. 2017

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Chem. Commun., 2017,53, 7274-7277

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Reversible dinitrogen binding to [Cp′Fe(NHC)] associated with an N₂-induced spin state change

M. Reiners, D. Baabe, M. Zaretzke, M. Freytag and M. D. Walter, Chem. Commun., 2017, 53, 7274 DOI: 10.1039/C7CC01535F

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