Issue 4, 2007

Asymmetric self-assembly with atmospheric CO2 fixation of a pentanuclear carbonate NiII complex based on dissimilar building blocks

Abstract

Formation in basic solution of an asymmetric pentanuclear carbonate NiII complex with a compartmental ligand involves atmospheric CO2 uptake, either by reaction of two slightly different dinuclear precursors that yield its di- and trinuclear “building blocks”, or directly, by spontaneous self-organization of metal and ligand starting reactants.

Graphical abstract: Asymmetric self-assembly with atmospheric CO2 fixation of a pentanuclear carbonate NiII complex based on dissimilar building blocks

Supplementary files

Article information

Article type
Communication
Submitted
28 Du 2006
Accepted
01 Ker. 2006
First published
12 Ker. 2006

Dalton Trans., 2007, 414-416

Asymmetric self-assembly with atmospheric CO2 fixation of a pentanuclear carbonate NiII complex based on dissimilar building blocks

M. Fondo, A. M. García-Deibe, N. Ocampo, J. Sanmartín and M. R. Bermejo, Dalton Trans., 2007, 414 DOI: 10.1039/B617374H

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