Molecular and heterogeneous water oxidation catalysts: recent progress and joint perspectives

J. Li, C. A. Triana, W. Wan, D. P. Adiyeri Saseendran, Y. Zhao, S. E. Balaghi, S. Heidari and G. R. Patzke

Chem. Soc. Rev., 2021, 50, 2444
DOI: 10.1039/D0CS00978D

Chemical design of metal complexes for electrochemical water oxidation under acidic conditions

Zhen-Tao Yu

Dalton Trans., 2025, 54, 2718
DOI: 10.1039/D4DT02874K

An intramolecular cobalt-peptoid complex as an efficient electrocatalyst for water oxidation at low overpotential

Suraj Pahar and Galia Maayan

Chem. Sci., 2024, 15, 12928
DOI: 10.1039/D4SC01182A

Zinc porphyrin/mesoporous titania thin film electrodes: a hybrid material nanoarchitecture for photocatalytic reduction

Rolando M. Caraballo, Priscila Vensaus, Facundo C. Herrera, Galo J. A. A. Soler Illia and Mariana Hamer

RSC Adv., 2021, 11, 31124
DOI: 10.1039/D1RA06585H

Blocking the bimolecular pathway of water oxidation electrocatalyzed by copper porphyrin with a surfactant

Luna Yang, Shujiao Yang, Jiafan Kong, Wenjie Yuan, Sisi Li, Xiaohan Liu, Rui Cao and Wei Zhang

Catal. Sci. Technol., 2024, 14, 3131
DOI: 10.1039/D4CY00292J

Significantly improved electrocatalytic oxygen reduction by an asymmetrical Pacman dinuclear cobalt(ii) porphyrin–porphyrin dyad

Yanju Liu, Guojun Zhou, Zongyao Zhang, Haitao Lei, Zhen Yao, Jianfeng Li, Jun Lin and Rui Cao

Chem. Sci., 2020, 11, 87
DOI: 10.1039/C9SC05041H

Electrochemical water oxidation using single-site Cu(ii) molecular complexes: a mechanism elucidated by computational studies

Dev Raj, Koushik Makhal, Manaswini Raj, Aman Mishra, Rohan Mahapatra, Tanya Pattnaik, Bhabani S. Mallik and Sumanta Kumar Padhi

Dalton Trans., 2025, 54, 13894
DOI: 10.1039/D5DT01397F

Electronic and energy level engineering of directly fused porphyrin-conjugated polymers – impact of the central metal cation

Drialys Cardenas-Morcoso, Eloa Vey, Max Heiderscheid, Gilles Frache and Nicolas D. Boscher

J. Mater. Chem. C, 2022, 10, 2194
DOI: 10.1039/D1TC05452J

Electrochemical water oxidation by a copper complex with an N4-donor ligand under neutral conditions

Junqi Lin, Xin Chen, Nini Wang, Shanshan Liu, Zhijun Ruan and Yanmei Chen

Catal. Sci. Technol., 2021, 11, 6470
DOI: 10.1039/D1CY01183A

Efficient homogeneous electrochemical water oxidation by a copper(ii) complex with a hexaaza macrotricyclic ligand

Junqi Lin, Shenke Zheng, Li Hong, Xueli Yang, Weixiang Lv, Yichang Li, Chang Dai, Shanshan Liu and Zhijun Ruan

New J. Chem., 2022, 46, 14642
DOI: 10.1039/D2NJ02449G

Transition metal-mediated O–O bond formation and activation in chemistry and biology

Xue-Peng Zhang, Anirban Chandra, Yong-Min Lee, Rui Cao, Kallol Ray and Wonwoo Nam

Chem. Soc. Rev., 2021, 50, 4804
DOI: 10.1039/D0CS01456G

Efficient visible light-driven water oxidation catalysed by an iron(iv) clathrochelate complex

Sergii I. Shylin, Mariia V. Pavliuk, Luca D’Amario, Fikret Mamedov, Jacinto Sá, Gustav Berggren and Igor O. Fritsky

Chem. Commun., 2019, 55, 3335
DOI: 10.1039/C9CC00229D

Ultrastable 3D cage-like metal–organic frameworks constructed using polydentate cyanurate ligands and their gas adsorption properties

Wenhao Xing, Kaijin Kang, Jian Tang, Chunlan Tang, Wenlong Yin, Bin Kang and Jianguo Deng

Dalton Trans., 2023, 52, 10183
DOI: 10.1039/D3DT01317K

Supramolecular cages and metal organic frameworks of porphyrins for a sustainable tomorrow: challenges and applications

Kharu Nisa, Megha Saxena, Ishfaq Ahmad Lone and Ravi Kumar

Sustainable Energy Fuels, 2023, 7, 2774
DOI: 10.1039/D3SE00350G

Efficient electrochemical water oxidation mediated by a binuclear copper complex with a helical structure

Qiuxian Bai, Xueli Yang, Shenke Zheng, Li Hong, Chang Dai, Junqi Lin, Pei Wang and Xiangming Liang

Sustainable Energy Fuels, 2022, 6, 3643
DOI: 10.1039/D2SE00695B

Repurposing a peptide antibiotic as a catalyst: a multicopper–daptomycin complex as a cooperative O–O bond formation and activation catalyst

Yen Jea Lee, Haesol Kim, Yujeong Kim, Kang Hee Cho, Sugyeong Hong, Ki Tae Nam, Sun Hee Kim, Chang Hyuck Choi and Jiwon Seo

Inorg. Chem. Front., 2022, 9, 4741
DOI: 10.1039/D2QI01440H

Electrocatalytic oxidation of water using self-assembled copper(ii) tetraaza macrocyclic complexes on a 4-(pyridine-4′-amido)benzene grafted gold electrode

Abhinandan Mahanta, Koushik Barman, Umme Solaem Akond and Sk Jasimuddin

New J. Chem., 2021, 45, 8676
DOI: 10.1039/D1NJ00630D

Selective two-electron and four-electron oxygen reduction reactions using Co-based electrocatalysts

Zuozhong Liang, Haitao Lei, Haoquan Zheng, Hong-Yan Wang, Wei Zhang and Rui Cao

Chem. Soc. Rev., 2025, 54, 5248
DOI: 10.1039/D4CS01199F

Design of molecular water oxidation catalysts with earth-abundant metal ions

Mio Kondo, Hayato Tatewaki and Shigeyuki Masaoka

Chem. Soc. Rev., 2021, 50, 6790
DOI: 10.1039/D0CS01442G

Homogeneous photochemical water oxidation with metal salophen complexes in neutral media

Md. Ali Asraf, Chizoba I. Ezugwu, C. M. Zakaria and Francis Verpoort

Photochem Photobiol Sci, 2019, 18, 2782
DOI: 10.1039/c9pp00254e

Water electrolysis: from textbook knowledge to the latest scientific strategies and industrial developments

Marian Chatenet, Bruno G. Pollet, Dario R. Dekel, Fabio Dionigi, Jonathan Deseure, Pierre Millet, Richard D. Braatz, Martin Z. Bazant, Michael Eikerling, Iain Staffell, Paul Balcombe, Yang Shao-Horn and Helmut Schäfer

Chem. Soc. Rev., 2022, 51, 4583
DOI: 10.1039/D0CS01079K

A Co-tris coordination complex as a stable homogeneous electrocatalyst for aqueous water oxidation

Debu Jana, Kalipada Paul and Samar K. Das

Dalton Trans., 2026, 55, 2718
DOI: 10.1039/D5DT02512E

Electrochemical generation of high-valent oxo-manganese complexes featuring an anionic N5 ligand and their role in O–O bond formation

Sachidulal Biswas, Srijan Narayan Chowdhury, Panjo Lepcha, Subhankar Sutradhar, Abhishek Das, Tapan Kanti Paine, Satadal Paul and Achintesh N. Biswas

Dalton Trans., 2023, 52, 16616
DOI: 10.1039/D3DT02740F

Light-driven water oxidation by a BiVO4/TiO2 photoanode modified with D102 organic dye and copper(ii) meso-tetra(4-carboxyphenyl)porphyrin

Andi Mauliana, Muhammad Iqbal Syauqi, Zico Alaia Akbar, Uji Pratomo, Jacob Yan Mulyana and Tribidasari A. Ivandini

Sustainable Energy Fuels, 2024, 8, 5927
DOI: 10.1039/D4SE00543K

Cobalt porphyrin intercalation into zirconium phosphate layers for electrochemical water oxidation

Isabel Barraza Alvarez, Yanyu Wu, Joel Sanchez, Yulu Ge, Mario V. Ramos-Garcés, Tong Chu, Thomas F. Jaramillo, Jorge L. Colón and Dino Villagrán

Sustainable Energy Fuels, 2021, 5, 430
DOI: 10.1039/D0SE01134G

Theoretical study on the mechanism of water oxidation catalyzed by a mononuclear copper complex: important roles of a redox non-innocent ligand and HPO42−anion

Ying-Ying Li, Xiao-Yan Wang, Hui-Ji Li, Jia-Yi Chen, Yao-Hua Kou, Xiao Li and Yaping Wang

RSC Adv., 2023, 13, 8352
DOI: 10.1039/D3RA00648D

Significantly boosted oxygen electrocatalysis with cooperation between cobalt and iron porphyrins

Haitao Lei, Qingxin Zhang, Yabo Wang, Yimei Gao, Yanzhi Wang, Zuozhong Liang, Wei Zhang and Rui Cao

Dalton Trans., 2021, 50, 5120
DOI: 10.1039/D1DT00441G

Base-enhanced electrochemical water oxidation by a nickel complex in neutral aqueous solution

Lu-Hua Zhang, Fengshou Yu, Yumeng Shi, Fei Li and Henan Li

Chem. Commun., 2019, 55, 6122
DOI: 10.1039/C9CC01865D

Boosting water oxidation activity by tuning the proton transfer process of cobalt phosphonates in neutral solution

Jiangquan Lv, Xiangfeng Guan, Muxin Yu, Xiaoyan Li, Yunlong Yu and Dagui Chen

Phys. Chem. Chem. Phys., 2020, 22, 14255
DOI: 10.1039/D0CP02194F

Porphyrin-based frameworks for oxygen electrocatalysis and catalytic reduction of carbon dioxide

Zuozhong Liang, Hong-Yan Wang, Haoquan Zheng, Wei Zhang and Rui Cao

Chem. Soc. Rev., 2021, 50, 2540
DOI: 10.1039/D0CS01482F

Understanding the factors governing the water oxidation reaction pathway of mononuclear and binuclear cobalt phthalocyanine catalysts

Qing'e Huang, Jun Chen, Peng Luan, Chunmei Ding and Can Li

Chem. Sci., 2022, 13, 8797
DOI: 10.1039/D2SC02213C

Bifunctional porphyrin-based metal–organic polymers for electrochemical water splitting

Neidy Ocuane, Yulu Ge, Christian Sandoval-Pauker and Dino Villagrán

Dalton Trans., 2024, 53, 2306
DOI: 10.1039/D3DT03371F

Dicopper(ii) tetrapyridyl complexes incorporated with ancillary ligands for effective water oxidation

Wen-Hui Pi, Qi-Jun Li, Min Wu, Xiao-Lin Zhou, Jia-Ni Wei, Xian-Hong Zhu and Hua-Xin Zhang

New J. Chem., 2020, 44, 12194
DOI: 10.1039/D0NJ00624F

Chemical and electrochemical water oxidation mediated by bis(pyrazol-1-ylmethyl)pyridine-ligated Cu(i) complexes

T. Makhado, B. Das, R. J. Kriek, H. C. M. Vosloo and A. J. Swarts

Sustainable Energy Fuels, 2021, 5, 2771
DOI: 10.1039/D1SE00402F

Carbon quantum dots aqueous solution as electrolyte for H2O2 production based on photoelectrochemical water splitting

Na Wang, Yong-Shuai Zhang, Dong-Dong Wei, Hui-Min Duan, Liu-Meng Mo and Hong-Yan Wang

J. Mater. Chem. A, 2023, 11, 4162
DOI: 10.1039/D2TA09453C

A two-dimensional multi-shelled metal–organic framework and its derived bimetallic N-doped porous carbon for electrocatalytic oxygen reduction

Yang Xu, Zhehao Huang, Bin Wang, Zuozhong Liang, Chaochao Zhang, Yanzhi Wang, Wei Zhang, Haoquan Zheng and Rui Cao

Chem. Commun., 2019, 55, 14805
DOI: 10.1039/C9CC08250F

A COOH-terminated nitrogen-doped carbon aerogel as a bulk electrode for completely selective two-electron oxygen reduction to H2O2

Hongying Zhao, Xuqian Shen, Ying Chen, Shi-Nan Zhang, Peng Gao, Xiangjun Zhen, Xin-Hao Li and Guohua Zhao

Chem. Commun., 2019, 55, 6173
DOI: 10.1039/C9CC02580D

Electrogelation of PEDOT:PSS and its copolymer for bioelectronics

Christopher Slaughter, Santiago Velasco-Bosom, Xudong Tao, Ruben Ruiz-Mateos Serrano, Stefany Kissovsky, Ryo Mizuta, Daniele Mantione, Scott T. Keene, George G. Malliaras and Antonio Dominguez-Alfaro

J. Mater. Chem. C, 2024, 12, 14944
DOI: 10.1039/D4TC02908A

Functional carbon nitride materials for water oxidation: from heteroatom doping to interface engineering

Huayang Zhang, Wenjie Tian, Xiaoguang Duan, Hongqi Sun, Yonglong Shen, Guosheng Shao and Shaobin Wang

Nanoscale, 2020, 12, 6937
DOI: 10.1039/D0NR00652A

A low-cost commercial Cu(ii)–EDTA complex for electrocatalytic water oxidation in neutral aqueous solution

Kaishan Yu, Yue Sun, Dingwei Zhu, Ziyi Xu, Jiayi Wang, Junyu Shen, Qijian Zhang and Wei Zhao

Chem. Commun., 2022, 58, 12835
DOI: 10.1039/D2CC04846A

A unique Co(iii)-peptoid as a fast electrocatalyst for homogeneous water oxidation with low overpotential

Guilin Ruan, Lee Engelberg, Pritam Ghosh and Galia Maayan

Chem. Commun., 2021, 57, 939
DOI: 10.1039/D0CC06912D

Copper-based homogeneous and heterogeneous catalysts for electrochemical water oxidation

Husileng Lee, Xiujuan Wu and Licheng Sun

Nanoscale, 2020, 12, 4187
DOI: 10.1039/C9NR10437B

Constructing a biomimetic TiOF2@PCN-222-Fe Z-scheme heterojunction using self-assembled L-cysteine for CO2 visible light photoreduction

Yi Ping, Chuanjiao Wang, Changan Hou, Zhenfeng Shang and Danhong Wang

Mater. Horiz., 2025, 12, 4724
DOI: 10.1039/D5MH00272A

Impact of the hybridization form of the coordinated nitrogen atom on the electrocatalytic water oxidation performance of copper complexes with pentadentate amine-pyridine ligands

Kaishan Yu, Tao Wang, Yue Sun, Mei Kang, Xinxin Wang, Dingwei Zhu, Siyi Xue, Junyu Shen, Qijian Zhang and Jinxuan Liu

Dalton Trans., 2024, 53, 612
DOI: 10.1039/D3DT03185C

Stoichiometric and electrocatalytic production of hydrogen peroxide driven by a water-soluble copper(ii) complex

Hana Oh, Suhyuk Choi, Joo Yeon Kim, Hyun S. Ahn and Seungwoo Hong

Chem. Commun., 2019, 55, 12659
DOI: 10.1039/C9CC06956A

Structural evolution of the Ru-bms complex to the real water oxidation catalyst of Ru-bda: the bite angle matters

Jing Yang, Bin Liu and Lele Duan

Dalton Trans., 2020, 49, 4369
DOI: 10.1039/C9DT04693C

Metalloporphyrin immobilized CeO2: in situ generation of active sites and synergistic promotion of photocatalytic water oxidation

Jiao Meng, Yue Zhao, Haining Li, Ruiping Chen, Xun Sun and Xuan Sun

Catal. Sci. Technol., 2021, 11, 2560
DOI: 10.1039/D0CY02409K

Electrocatalytic water oxidation by a water-soluble copper complex with a pentadentate amine-pyridine ligand

Ziyi Xu, Zilin Zheng, Qi Chen, Jiayi Wang, Kaishan Yu, Xin Xia, Junyu Shen and Qijian Zhang

Dalton Trans., 2021, 50, 10888
DOI: 10.1039/D1DT01821C

High quantum yield photochemical water oxidation using a water-soluble cobalt phthalocyanine as a homogenous catalyst

Takashi Nakazono, Nagisa Amino, Risa Matsuda, Daichi Sugawara and Tohru Wada

Chem. Commun., 2022, 58, 7674
DOI: 10.1039/D2CC01985J

2D Metal–Organic Framework Derived CuCo Alloy Nanoparticles Encapsulated by Nitrogen‐Doped Carbonaceous Nanoleaves for Efficient Bifunctional Oxygen Electrocatalyst and Zinc–Air Batteries

Meiling Huo, Bin Wang, Chaochao Zhang, Shuping Ding, Haitao Yuan, Zuozhong Liang, Jing Qi, Mingxing Chen, Yang Xu, Wei Zhang, Haoquan Zheng and Rui Cao

Chemistry A European J, 2019, 25, 12780
DOI: 10.1002/chem.201902389

Role of transition metals in catalyst designs for oxygen evolution reaction: A comprehensive review

Yuan Feng, Haitao Yang, Xin Wang, Chaoquan Hu, Hailong Jing and Jiaxin Cheng

International Journal of Hydrogen Energy, 2022, 47, 17946
DOI: 10.1016/j.ijhydene.2022.03.270

Crucial Roles of a Pendant Imidazole Ligand of a Cobalt Porphyrin Complex in the Stoichiometric and Catalytic Reduction of Dioxygen

Jindou Yang, Ping Li, Xialiang Li, Lisi Xie, Ni Wang, Haitao Lei, Chaochao Zhang, Wei Zhang, Yong‐Min Lee, Weiqiang Zhang, Rui Cao, Shunichi Fukuzumi and Wonwoo Nam

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202208143

Integrating Homogeneous and Heterogeneous Catalytic Systems for Synergistic Water Oxidation: Role of Geometrically Distinct Bispidine Metal Complexes

Nitul Kalita, Jagnyesh K. Satpathy, Rolly Yadav, Chivukula V. Sastri and Mohammad Qureshi

Chem. Mater., 2025, 37, 2026
DOI: 10.1021/acs.chemmater.5c00049

Chiral Self-Assembly of Zinc and Magnesium Porphyrins with Enantiopure Cyclohexanohemicucurbiturils in Solution and in Solid State

Marko Šakarašvili, Khai-Nghi Truong, Lukáš Ustrnul, Nele Konrad, Kristjan Siilak, Tatsiana Burankova, Reiko Kuroda, Mathias O. Senge, Victor Borovkov, Jas S. Ward, Kari Rissanen and Riina Aav

Inorg. Chem., 2025, 64, 23773
DOI: 10.1021/acs.inorgchem.5c04969

Homogeneous Water Oxidation Catalyzed by First‐Row Transition Metal Complexes: Unveiling the Relationship between Turnover Frequency and Reaction Overpotential

Wan‐Chi Hsu and Yu‐Heng Wang

ChemSusChem, 2022, 15
DOI: 10.1002/cssc.202102378

Enzyme‐Inspired Iron Porphyrins for Improved Electrocatalytic Oxygen Reduction and Evolution Reactions

Lisi Xie, Xue‐Peng Zhang, Bin Zhao, Ping Li, Jing Qi, Xinai Guo, Bin Wang, Haitao Lei, Wei Zhang, Ulf‐Peter Apfel and Rui Cao

Angew Chem Int Ed, 2021, 60, 7576
DOI: 10.1002/anie.202015478

Computational Investigation on the Mechanism of Electrocatalytic Water Oxidation by Copper(II) Porphyrin

Shanti Gopal Patra, Chhanda Paul, Aritra Saha and Pratim Kumar Chattaraj

Advcd Theory and Sims, 2026, 9
DOI: 10.1002/adts.202501442

Coordination Tuning of Metal Porphyrins for Improved Oxygen Evolution Reaction

Haoyuan Lv, Xue‐Peng Zhang, Kai Guo, Jinxiu Han, Hongbo Guo, Haitao Lei, Xialiang Li, Wei Zhang, Ulf‐Peter Apfel and Rui Cao

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202305938

Bioinspired N4-metallomacrocycles for electrocatalytic oxygen reduction reaction

Yuliang Li, Ni Wang, Haitao Lei, Xialiang Li, Haoquan Zheng, Hongyan Wang, Wei Zhang and Rui Cao

Coordination Chemistry Reviews, 2021, 442, 213996
DOI: 10.1016/j.ccr.2021.213996

Electrochemical Water Oxidation Mechanisms Involving Macrocyclic Copper(II) Complexes: Ligand Ring Size Effects on Catalytic Cycles

João Pedro C. S. Neves, Roberto Rivelino, Tiago Vinicius Alves and Vitor H. Menezes da Silva

ChemPhysChem, 2026, 27
DOI: 10.1002/cphc.202500637

Rational Design of Covalent Heptazine Frameworks with Spatially Separated Redox Centers for High‐Efficiency Photocatalytic Hydrogen Peroxide Production

Hao Cheng, Haifeng Lv, Jun Cheng, Lei Wang, Xiaojun Wu and Hangxun Xu

Advanced Materials, 2022, 34
DOI: 10.1002/adma.202107480

Synthesis, Characterization and Reactivity Studies of Cobalt(III) Porphyrin‐Iodosylarene Adduct and Cobalt(III) Porphyrin π‐Cation Radical Species

Wenwen Fu, Shoujun Wang, Yuheng Zhang, Minghao Xu, Dongru Sun, Wonwoo Nam, Yong Wang and Mian Guo

ChemCatChem, 2024, 16
DOI: 10.1002/cctc.202400317

Metal‐Corrole‐Based Porous Organic Polymers for Electrocatalytic Oxygen Reduction and Evolution Reactions

Haitao Lei, Qingxin Zhang, Zuozhong Liang, Hongbo Guo, Yabo Wang, Haoyuan Lv, Xialiang Li, Wei Zhang, Ulf‐Peter Apfel and Rui Cao

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202201104

Reaction Intermediates in Artificial Photosynthesis with Molecular Catalysts

Young Hyun Hong, Yong-Min Lee, Wonwoo Nam and Shunichi Fukuzumi

ACS Catal., 2023, 13, 308
DOI: 10.1021/acscatal.2c05033

Accelerated Water Oxidation Kinetics Triggered by Supramolecular Porphyrin Nanosheet for Robust Visible‐Light‐Driven CO2 Reduction

Qian Chen, Yue Zhang, Enming You, Qiaorong Jiang, Xianjie Chen, Yu Wang, Zhijia Song, Kuan Chang, Zhaoxiong Xie and Qin Kuang

Small, 2022, 18
DOI: 10.1002/smll.202204924

Efficient and stable H2O2 production from H2O and O2 on BiPO4 photocatalyst

Chengsi Pan, Gaoming Bian, Yaning Zhang, Yang Lou, Ying Zhang, Yuming Dong, Jing Xu and Yongfa Zhu

Applied Catalysis B: Environmental, 2022, 316, 121675
DOI: 10.1016/j.apcatb.2022.121675

Molecular electrocatalysis: Metalloporphyrins for hydrogen evolution and oxygen evolution and oxygen reduction reactions

Sikai Wang, Zhimeng Wang, Haitao Lei, Xue-Peng Zhang, Xialiang Li and Rui Cao

Chin. Sci. Bull., 2024, 69, 4983
DOI: 10.1360/TB-2024-0942

2D coordination polymers: Design guidelines and materials perspective

Michael Tran, Katelyn Kline, Ying Qin, Yuxia Shen, Matthew D. Green and Sefaattin Tongay

Applied Physics Reviews, 2019, 6, 041311
DOI: 10.1063/1.5110895

Efficient Electrochemical Water Oxidation Mediated by Pyridylpyrrole-Carboxylate Ruthenium Complexes

Guo Chen, Ze-Wen Chen, Yuan-Mei Wang, Piao He, Chao Liu, Hai-Xia Tong and Xiao-Yi Yi

Inorg. Chem., 2021, 60, 15627
DOI: 10.1021/acs.inorgchem.1c02251

Enzyme‐Inspired Iron Porphyrins for Improved Electrocatalytic Oxygen Reduction and Evolution Reactions

Lisi Xie, Xue‐Peng Zhang, Bin Zhao, Ping Li, Jing Qi, Xinai Guo, Bin Wang, Haitao Lei, Wei Zhang, Ulf‐Peter Apfel and Rui Cao

Angewandte Chemie, 2021, 133, 7654
DOI: 10.1002/ange.202015478

Bimetallic two-dimensional materials for electrocatalytic oxygen evolution

Xiaojie Li, Qi Hu, Hengpan Yang, Tao Ma, Xiaoyan Chai and Chuanxin He

Chinese Chemical Letters, 2022, 33, 3657
DOI: 10.1016/j.cclet.2021.12.001

Morphology control and electronic tailoring of CoxAy (A = P, S, Se) electrocatalysts for water splitting

Jie Yu, Zheng Li, Tong Liu, Siyuan Zhao, Daqin Guan, Daifen Chen, Zongping Shao and Meng Ni

Chemical Engineering Journal, 2023, 460, 141674
DOI: 10.1016/j.cej.2023.141674

Pivotal Role of Geometry Regulation on O−O Bond Formation Mechanism of Bimetallic Water Oxidation Catalysts

Qi‐Fa Chen, Ke‐Lin Xian, Hong‐Tao Zhang, Xiao‐Jun Su, Rong‐Zhen Liao and Ming‐Tian Zhang

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202317514

Bioinspired Trinuclear Copper Catalyst for Water Oxidation with a Turnover Frequency up to 20000 s–1

Qi-Fa Chen, Ze-Yu Cheng, Rong-Zhen Liao and Ming-Tian Zhang

J. Am. Chem. Soc., 2021, 143, 19761
DOI: 10.1021/jacs.1c08078

Identifying an Active Intermediate and Monitoring O─O Bond Formation in Water Oxidation by a Cobalt(III)‐TAML Complex

Deesha D. Malik, Yong‐Min Lee, Shunichi Fukuzumi, Kallol Ray and Wonwoo Nam

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202516165

ZIF‐8 MOF Encapsulated Co‐porphyrin, an Efficient Electrocatalyst for Water Oxidation in a Wide pH Range: Works Better at Neutral pH

Subhabrata Mukhopadhyay, Olivia Basu and Samar K. Das

ChemCatChem, 2020, 12, 5430
DOI: 10.1002/cctc.202000804

A homogeneous cobalt complex mediated electro and photocatalytic O2/H2O interconversion in neutral water

Abhishek Saini, Chandan Das, Surabhi Rai, Aritra Guha, Dependu Dolui, Piyali Majumder and Arnab Dutta

iScience, 2023, 26, 108189
DOI: 10.1016/j.isci.2023.108189

Identifying Intermediates in Electrocatalytic Water Oxidation with a Manganese Corrole Complex

Xialiang Li, Xue-Peng Zhang, Mian Guo, Bin Lv, Kai Guo, Xiaotong Jin, Wei Zhang, Yong-Min Lee, Shunichi Fukuzumi, Wonwoo Nam and Rui Cao

J. Am. Chem. Soc., 2021, 143, 14613
DOI: 10.1021/jacs.1c05204

A Homogeneously Catalyzed Paired Electrolytic Cell for Hydrogen Peroxide Production

Caterina Trotta, Jesse Orta, Hendrik C. de Heer, Pim G. J. van Duren, Maxime A. Siegler, Gabriel Menendez Rodriguez, Alceo Macchioni and D. G. H. Hetterscheid

Angew Chem Int Ed, 2026
DOI: 10.1002/anie.202524811

Metalloporphyrin-based nanocatalysts for aerobic oxidation: A comparative evaluation

Saeed Rayati and Niloofar Pournaser

J. Porphyrins Phthalocyanines, 2026, 30, 137
DOI: 10.1142/S1088424625501081

Mono‐/Multinuclear Water Oxidation Catalysts

Qiaoqiao Zhang and Jingqi Guan

ChemSusChem, 2019, 12, 3209
DOI: 10.1002/cssc.201900704

Regenerable Catalyst for Highly Alkaline Water Oxidation

Mengjun Xiao, Qianbao Wu, Lei Li, Shijia Mu, Mads Nybo Sørensen, Wei Wang and Chunhua Cui

ACS Energy Lett., 2021, 6, 1677
DOI: 10.1021/acsenergylett.1c00127

Pivotal Role of Geometry Regulation on O−O Bond Formation Mechanism of Bimetallic Water Oxidation Catalysts

Qi‐Fa Chen, Ke‐Lin Xian, Hong‐Tao Zhang, Xiao‐Jun Su, Rong‐Zhen Liao and Ming‐Tian Zhang

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202317514

Redox Non‐Innocent Ligand Assisted Electrocatalytic Water Oxidation Catalyzed by a Molecular Cobalt Complex

Afsar Ali, Avijit Das, Aakash Santra, Rajaneesh Kumar Verma and Sayantan Paria

ChemCatChem, 2025, 17
DOI: 10.1002/cctc.202500652

Bidirectional O2 reduction/H2O oxidation boosted by a pentadentate pyridylalkylamine copper(II) complex

Xiao Zhang, Gui-Shan Chen, Hao-Cheng Liu, Ming-Jun Zhu, Ming-Yi Xie, Ming-Sheng Cen, Qi-Jun Li, Tian-Shun Wang and Hua-Xin Zhang

Electrochimica Acta, 2023, 446, 142099
DOI: 10.1016/j.electacta.2023.142099

Stabilization of *OH intermediates for enhanced photocatalytic H2O oxidation to H2O2

Xinyu Sun, Tingyu Yang, Yuming Dong, Rong Ji, Hui Zhao, Jiawei Zhang, Chengsi Pan and Yongfa Zhu

Applied Catalysis B: Environment and Energy, 2025, 379, 125692
DOI: 10.1016/j.apcatb.2025.125692

Copper coordination polymer with lattice water molecules and strong electrocatalytic OER activity

Pandi Muthukumar, Gunasekaran Arunkumar, Mehboobali Pannipara, Abdullah G. Al-Sehemi, Dohyun Moon and Savarimuthu Philip Anthony

Results in Chemistry, 2023, 6, 101140
DOI: 10.1016/j.rechem.2023.101140

Advanced Electrocatalysts with Single-Metal-Atom Active Sites

Yuxuan Wang, Hongyang Su, Yanghua He, Ligui Li, Shangqian Zhu, Hao Shen, Pengfei Xie, Xianbiao Fu, Guangye Zhou, Chen Feng, Dengke Zhao, Fei Xiao, Xiaojing Zhu, Yachao Zeng, Minhua Shao, Shaowei Chen, Gang Wu, Jie Zeng and Chao Wang

Chem. Rev., 2020, 120, 12217
DOI: 10.1021/acs.chemrev.0c00594

Bio-Inspired Molecular Catalysts for Water Oxidation

Dan Xiao, Jennifer Gregg, K. V. Lakshmi and Peter J. Bonitatibus

Catalysts, 2021, 11, 1068
DOI: 10.3390/catal11091068

Buffer anion effects on water oxidation catalysis: The case of Cu(III) complex

Qifa Chen, Haoyi Du and Mingtian Zhang

Chinese Journal of Catalysis, 2021, 42, 1338
DOI: 10.1016/S1872-2067(20)63729-9

Identifizierung eines aktiven Intermediats und Beobachtung der O–O‐Bindungsbildung bei der Wasseroxidation durch einen Cobalt(III)‐TAML‐Komplex

Deesha D. Malik, Yong‐Min Lee, Shunichi Fukuzumi, Kallol Ray and Wonwoo Nam

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202516165

Homogeneous Catalysts Based on First‐Row Transition‐Metals for Electrochemical Water Oxidation

Lu‐Hua Zhang, Simon Mathew, Joeri Hessels, Joost N. H. Reek and Fengshou Yu

ChemSusChem, 2021, 14, 234
DOI: 10.1002/cssc.202001876

2D Porphyrinic Metal-Organic Frameworks Featuring Rod-Shaped Secondary Building Units

Rory Elliott, Aoife A. Ryan, Aviral Aggarwal, Nianyong Zhu, Friedrich W. Steuber, Mathias O. Senge and Wolfgang Schmitt

Molecules, 2021, 26, 2955
DOI: 10.3390/molecules26102955

Unraveling group dynamics in alkaline electrochemical water splitting using β-substituted porphyrinoids

Ishfaq Ahmad Lone and Ravi Kumar

Inorganica Chimica Acta, 2025, 576, 122453
DOI: 10.1016/j.ica.2024.122453

Photochemical Water Oxidation Using a Doubly N-Confused Hexaphyrin Dinuclear Cobalt Complex

Takashi Nakazono and Tohru Wada

Inorg. Chem., 2021, 60, 1284
DOI: 10.1021/acs.inorgchem.0c02602

Crucial Roles of a Pendant Imidazole Ligand of a Cobalt Porphyrin Complex in the Stoichiometric and Catalytic Reduction of Dioxygen

Jindou Yang, Ping Li, Xialiang Li, Lisi Xie, Ni Wang, Haitao Lei, Chaochao Zhang, Wei Zhang, Yong‐Min Lee, Weiqiang Zhang, Rui Cao, Shunichi Fukuzumi and Wonwoo Nam

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202208143

Structure Effects of Metal Corroles on Energy-Related Small Molecule Activation Reactions

Haitao Lei, Xialiang Li, Jia Meng, Haoquan Zheng, Wei Zhang and Rui Cao

ACS Catal., 2019, 9, 4320
DOI: 10.1021/acscatal.9b00310

Copper Coordination Complexes for Energy-Relevant Applications

Iacopo Benesperi, Reena Singh and Marina Freitag

Energies, 2020, 13, 2198
DOI: 10.3390/en13092198

New porphyrin photosensitizers—Synthesis, singlet oxygen yield, photophysical properties and application in PDT

Xiaorong Wang, Hui Lv, Yingkai Sun, Guoping Zu, Xiaozhen Zhang, Yufang Song, Fengyang Zhao and Jingang Wang

Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2022, 279, 121447
DOI: 10.1016/j.saa.2022.121447

Biomimetic Second Coordination Sphere Effect within Cu-Peptoid Electrocatalyst Enables Homogeneous Water Oxidation at pH 7

Guilin Ruan, Suraj Pahar, Natalia Fridman and Galia Maayan

Inorg. Chem., 2025, 64, 4267
DOI: 10.1021/acs.inorgchem.4c04501

Double-layer heterostructure in situ grown from stainless steel substrate for overall water splitting

Yuqiu Wu, Hongqin Luo, Chao Li, Xiao Lv, Ming Du, Hairen Wang and Jun-e Qu

Journal of Electroanalytical Chemistry, 2024, 954, 118029
DOI: 10.1016/j.jelechem.2024.118029

Tungsten Disulfide‐Interfacing Nickel‐Porphyrin For Photo‐Enhanced Electrocatalytic Water Oxidation

Michail P. Minadakis, Ruben Canton‐Vitoria, Christina Stangel, Emmanuel Klontzas, Raul Arenal, Javier Hernández‐Ferrer, Ana M. Benito, Wolfgang K. Maser and Nikos Tagmatarchis

ChemSusChem, 2023, 16
DOI: 10.1002/cssc.202202322

Synergistic Effect of Bio‐Inspired Microenvironment Modulation and Catalytic Site Design Enhances the Oxygen Evolution Performance of Copper‐Phenanthroline Catalysts

Mu‐Han Zhou, Tao Zheng, Rui‐Qi Li, Yi‐Lin Xie, Gui‐Lin Ruan, Fentahun Wondu Dagnaw, Xu‐Bing Li, Zhi‐Xing Wu, Qing‐Xiao Tong and Jing‐Xin Jian

Carbon Energy, 2025, 7
DOI: 10.1002/cey2.70063

Calcium-, magnesium-, and yttrium-doped lithium nickel phosphate nanomaterials as high-performance catalysts for electrochemical water oxidation reaction

Mehwish Huma Nasir, Hajira Niaz, Naila Yunus, Urooj Ali, Safia Khan, Tehmeena Maryum Butt, Hina Naeem, Hu Li, Mohamed A. Habila and Naveed Kausar Janjua

Nanotechnology Reviews, 2024, 13
DOI: 10.1515/ntrev-2023-0166

Soft Deposition of Organic Molecules Based on Cluster-Induced Desorption for the Investigation of On-Surface and Surface-Mediated Reactions

Karolin Pluschke, Aaron Herrmann and Michael Dürr

ACS Omega, 2023, 8, 40639
DOI: 10.1021/acsomega.3c05518

Tuning Proton Reduction Efficiencies of Copper Corrole in Electrocatalysis via Multiple β-Chloro Substitution

Kolanu Sudhakar and Pradeepta K. Panda

ACS Appl. Energy Mater., 2022, 5, 13492
DOI: 10.1021/acsaem.2c02165

A Bifunctional Electrocatalyst based on Ni-porphyrin/Vapor-Grown Carbon Fibres for Oxygen Reduction and Evolution Reactions in Alkaline Media

Ibrahim Elghamry, Abdulrahman S. Alablan and Mamdouh E. Abdelsalam

International Journal of Electrochemical Science, 2022, 17, 221013
DOI: 10.20964/2022.10.22

Electrochemical Synthesis of H2O2 by Two-Electron Water Oxidation Reaction

Xinjian Shi, Seoin Back, Thomas Mark Gill, Samira Siahrostami and Xiaolin Zheng

Chem, 2021, 7, 38
DOI: 10.1016/j.chempr.2020.09.013

Highly Efficient Catalytic Two-Electron Two-Proton Reduction of Dioxygen to Hydrogen Peroxide with a Cobalt Corrole Complex

Atanu Rana, Yong-Min Lee, Xialiang Li, Rui Cao, Shunichi Fukuzumi and Wonwoo Nam

ACS Catal., 2021, 11, 3073
DOI: 10.1021/acscatal.0c05003

Electropolymerization of cobalt porphyrins and corroles for the oxygen evolution reaction

Qingxin Zhang, Yabo Wang, Yanzhi Wang, Shujiao Yang, Xuan Wu, Bin Lv, Ni Wang, Yimei Gao, Xiaoran Xu, Haitao Lei and Rui Cao

Chinese Chemical Letters, 2021, 32, 3807
DOI: 10.1016/j.cclet.2021.04.048

An immobilized (carbene)nickel catalyst for water oxidation

Zhiyao Lu, Debanjan Mitra, Sri R. Narayan and Travis J. Williams

Polyhedron, 2024, 252, 116880
DOI: 10.1016/j.poly.2024.116880

Recent Advances in Electrocatalytic Two-Electron Water Oxidation for Green H2O2 Production

Liu Lin, Zemin Sun, Huatian Chen, Lian Zhao, Mingyue Sun, Yitao Yang, Zhensheng Liao, Xinyu Wu, Xinxin Li and Cheng Tang

Acta Physico-Chimica Sinica, 2024, 40, 2305019
DOI: 10.3866/PKU.WHXB202305019

Boosting photoanodic activity for water splitting in carbon dots aqueous solution without any traditional supporting electrolyte

Hong-Yan Wang, Rong Hu, Na Wang, Gui-Lin Hu, Kai Wang, Wei-Hua Xie and Rui Cao

Applied Catalysis B: Environmental, 2021, 296, 120378
DOI: 10.1016/j.apcatb.2021.120378

Organic carboxylate-based MOFs and derivatives for electrocatalytic water oxidation

Dongxu Yang, Yuanfu Chen, Zhe Su, Xiaojuan Zhang, Wanli Zhang and Katam Srinivas

Coordination Chemistry Reviews, 2021, 428, 213619
DOI: 10.1016/j.ccr.2020.213619

Coordination Tuning of Metal Porphyrins for Improved Oxygen Evolution Reaction

Haoyuan Lv, Xue‐Peng Zhang, Kai Guo, Jinxiu Han, Hongbo Guo, Haitao Lei, Xialiang Li, Wei Zhang, Ulf‐Peter Apfel and Rui Cao

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202305938

Underevaluated Solvent Effects in Electrocatalytic CO2 Reduction by FeIII Chloride Tetrakis(pentafluorophenyl)porphyrin

Bin Zhao, Haitao Lei, Ni Wang, Gelun Xu, Wei Zhang and Rui Cao

Chemistry A European J, 2020, 26, 4007
DOI: 10.1002/chem.201903064

Catalysis of a Single Transition Metal Site for Water Oxidation: From Mononuclear Molecules to Single Atoms

Huayang Zhang, Wenjie Tian, Xiaoguang Duan, Hongqi Sun, Shaomin Liu and Shaobin Wang

Advanced Materials, 2020, 32
DOI: 10.1002/adma.201904037

Cobalt Carbonate as an Electrocatalyst for Water Oxidation

Shanti G. Patra, Erzsébet Illés, Amir Mizrahi and Dan Meyerstein

Chemistry A European J, 2020, 26, 711
DOI: 10.1002/chem.201904051

Zeolite Imidazole Framework-Derived Hollow Nickel–Cobalt Layered Double Hydroxide Intercalated with Metalloporphyrin for Enhanced Oxygen Evolution Reaction

Yajun Fu, Zhengkun Ji, Xinhao Li, Abing Guo, Zichao Gao and Weijun Yang

Inorg. Chem., 2025, 64, 3213
DOI: 10.1021/acs.inorgchem.4c04351

Oxygen Evolution/Reduction Reaction Catalysts: From In Situ Monitoring and Reaction Mechanisms to Rational Design

Yonggui Zhao, Devi Prasad Adiyeri Saseendran, Chong Huang, Carlos A. Triana, Walker R. Marks, Hang Chen, Han Zhao and Greta R. Patzke

Chem. Rev., 2023, 123, 6257
DOI: 10.1021/acs.chemrev.2c00515

Recent progress on metalloporphyrin-based hydrogen evolution catalysis

Belete B. Beyene and Chen-Hsiung Hung

Coordination Chemistry Reviews, 2020, 410, 213234
DOI: 10.1016/j.ccr.2020.213234

Tricopper-polyoxometalate catalysts for water oxidation: Redox-inertness of copper center

Xiao-Fang Su, Wei Guan, Li-Kai Yan and Zhong-Min Su

Journal of Catalysis, 2020, 381, 402
DOI: 10.1016/j.jcat.2019.11.025

Molecular Engineering of Porphyrins for Near-Infrared Bioimaging and Phototherapy

Chulin Qu, Fan Wu and Zhen Shen

Chemical & Biomedical Imaging, 2025
DOI: 10.1021/cbmi.5c00214

Aggregation‐Induced Improvement of Catalytic Activity by Inner‐Aggregate Electronic Communication of Metal‐Fullerene‐Based Surfactants

Marius Kunkel, Stefan Bitter, Frank Sailer, Rainer F. Winter and Sebastian Polarz

ChemCatChem, 2020, 12, 2726
DOI: 10.1002/cctc.202000412

Exploring Group Interaction Patterns of Meso-Substituted Porphyrinoids on the Alkaline Electrochemical Water Splitting

Ishfaq Ahmad Lone, Anjumun Rasool, Kharu Nisa, Tahir Ahmad Dar, Nisar Ahmad Chopan, Ravi Kumar, Manzoor Ahmad Dar and Malik Wahid

Langmuir, 2025, 41, 16905
DOI: 10.1021/acs.langmuir.5c01277

Comparing electrocatalytic hydrogen and oxygen evolution activities of first-row transition metal complexes with similar coordination environments

Xiaotong Jin, Xialiang Li, Haitao Lei, Kai Guo, Bin Lv, Hongbo Guo, Dandan Chen, Wei Zhang and Rui Cao

Journal of Energy Chemistry, 2021, 63, 659
DOI: 10.1016/j.jechem.2021.08.068

Artificial Small Molecules as Cofactors and Biomacromolecular Building Blocks in Synthetic Biology: Design, Synthesis, Applications, and Challenges

Fenghua Liu, Lingling He, Sheng Dong, Jinsong Xuan, Qiu Cui and Yingang Feng

Molecules, 2023, 28, 5850
DOI: 10.3390/molecules28155850

Acetylene and Diacetylene Functionalized Covalent Triazine Frameworks as Metal‐Free Photocatalysts for Hydrogen Peroxide Production: A New Two‐Electron Water Oxidation Pathway

Liang Chen, Lei Wang, Yangyang Wan, Ying Zhang, Zeming Qi, Xiaojun Wu and Hangxun Xu

Advanced Materials, 2020, 32
DOI: 10.1002/adma.201904433

Electrocatalytic Water Oxidation with Surface Anchored Mononuclear Manganese (II) ‐ Polypyridine Complexes

Abhinandan Mahanta, Koushik Barman and Sk Jasimuddin

ChemistrySelect, 2019, 4, 11740
DOI: 10.1002/slct.201902953

Electrocatalytic Water Oxidation by Mononuclear Cu(II) Aliphatic Tetraamine Complexes

Huan Dong, Jialei Du, Jianfei Kong, Xiaoming He and Zuofeng Chen

ChemCatChem, 2019, 11, 5306
DOI: 10.1002/cctc.201900033

Efficient Co@Co3O4 core-shell catalysts for photocatalytic water oxidation and its behaviors in two different photocatalytic systems

Di Wang, Shanshan Qiao, Jia Guo, Yuan Guo, Qian Xu, Naeem Akram and Jide Wang

Journal of Energy Chemistry, 2021, 57, 83
DOI: 10.1016/j.jechem.2020.09.005

Reactivity of Nickel(II) Porphyrins in oCVD Processes—Polymerisation, Intramolecular Cyclisation and Chlorination

Giuseppe Bengasi, Kamal Baba, Oliver Back, Gilles Frache, Katja Heinze and Nicolas D. Boscher

Chemistry A European J, 2019, 25, 8313
DOI: 10.1002/chem.201900793

Strategies for Engineering High‐Performance PGM‐Free Catalysts toward Oxygen Reduction and Evolution Reactions

Lei Du, Lixin Xing, Gaixia Zhang, Marc Dubois and Shuhui Sun

Small Methods, 2020, 4
DOI: 10.1002/smtd.202000016

Electrocatalytic Water Oxidation Activity of Molecular Copper Complexes: Effect of Redox-Active Ligands

Moumita Bera, Kritika Keshari, Akhil Bhardwaj, Geetika Gupta, Bhaskar Mondal and Sayantan Paria

Inorg. Chem., 2022, 61, 3152
DOI: 10.1021/acs.inorgchem.1c03537

β-Functionalized Push–Pull Monobenzoporphyrins: Synthesis, Photophysical, Structural Properties, and Electrocatalytic Hydrogen Evolution by Their Co(II) Complexes

Waseem Arif, Shah Jahan Ul Islam, Muzaffar Ahmad Bhat, Vipin Kumar, Prabhakar Chetti, Vivek Kumar and Ravi Kumar

Inorg. Chem., 2025, 64, 16640
DOI: 10.1021/acs.inorgchem.5c02889

Controlled development of higher-dimensional nanostructured copper oxide thin films as binder free electrocatalysts for oxygen evolution reaction

Farhan Arshad, Akhtar Munir, Qasim Qayyum Kashif, Tanveer ul Haq, Javed Iqbal, Falak Sher and Irshad Hussain

International Journal of Hydrogen Energy, 2020, 45, 16583
DOI: 10.1016/j.ijhydene.2020.04.152

O–O bond formation mechanisms during the oxygen evolution reaction over synthetic molecular catalysts

Xue-Peng Zhang, Hong-Yan Wang, Haoquan Zheng, Wei Zhang and Rui Cao

Chinese Journal of Catalysis, 2021, 42, 1253
DOI: 10.1016/S1872-2067(20)63681-6

Ultra‐thin Co−Fe Layered Double Hydroxide Hollow Nanocubes for Efficient Electrocatalytic Water Oxidation

Haitao Yuan, Yanzhi Wang, Chenxi Yang, Zuozhong Liang, Mingxing Chen, Wei Zhang, Haoquan Zheng and Rui Cao

ChemPhysChem, 2019, 20, 2964
DOI: 10.1002/cphc.201900524

A One‐Pot Three‐In‐One Synthetic Strategy to Immobilize Cobalt Corroles on Carbon Nanotubes for Oxygen Electrocatalysis

Xialiang Li, Haonan Qin, Jinxiu Han, Xiaotong Jin, Yuhan Xu, Shujiao Yang, Wei Zhang and Rui Cao

Adv Funct Materials, 2024, 34
DOI: 10.1002/adfm.202310820

Electrocatalytic Water Oxidation by Mononuclear Copper Complexes of Bis-amide Ligands with N4 Donor: Experimental and Theoretical Investigation

Sahanwaj Khan, Swaraj Sengupta, Md. Adnan Khan, Md. Palashuddin Sk, Narayan Ch. Jana and Subhendu Naskar

Inorg. Chem., 2024, 63, 1888
DOI: 10.1021/acs.inorgchem.3c03512

Proton‐Coupled Electron Transfer in Electrocatalytic Water Splitting

Shujiao Yang, Jinxiu Han and Wei Zhang

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202302770

Binuclear Metal Phthalocyanines with Enhanced Activity in the Oxygen Evolution Reaction: A First-Principles Study

Jun Chen, Yang Liu, Ruizhi Duan, Qinge Huang and Can Li

J. Phys. Chem. Lett., 2024, 15, 3336
DOI: 10.1021/acs.jpclett.4c00363

Observation of a potential-dependent switch of water-oxidation mechanism on Co-oxide-based catalysts

Chaochao Lang, Jingyi Li, Ke R. Yang, Yuanxing Wang, Da He, James E. Thorne, Seth Croslow, Qi Dong, Yanyan Zhao, Gabriela Prostko, Gary W. Brudvig, Victor S. Batista, Matthias M. Waegele and Dunwei Wang

Chem, 2021, 7, 2101
DOI: 10.1016/j.chempr.2021.03.015

Elucidation of Factors That Govern the 2e–/2H+ vs 4e–/4H+ Selectivity of Water Oxidation by a Cobalt Corrole

Biswajit Mondal, Samir Chattopadhyay, Subal Dey, Atif Mahammed, Kaustuv Mittra, Atanu Rana, Zeev Gross and Abhishek Dey

J. Am. Chem. Soc., 2020, 142, 21040
DOI: 10.1021/jacs.0c08654

Through‐Space Electrostatic Effects of Positively Charged Substituents on the Hydrogen Evolution Reaction

Qingxin Zhang, Haitao Lei, Hongbo Guo, Yabo Wang, Yimei Gao, Wei Zhang and Rui Cao

ChemSusChem, 2022, 15
DOI: 10.1002/cssc.202200086

Synergy of copper doping and oxygen vacancies in porous CoOOH nanoplates for efficient water oxidation

Liang Yan, Bing Zhang, Zhonggang Liu and Junlu Zhu

Chemical Engineering Journal, 2021, 405, 126198
DOI: 10.1016/j.cej.2020.126198

A Glutamate-Enabled Proton Relay in a Bioinspired Cu4O4 Cubane Boosts Neutral Water Oxidation via Proton-Coupled Electron Transfer

Mu-Han Zhou, Tao Zheng, Wei Li, Ru-Qian Li, Wen-Chao Huang, Tie-Yu Wang, Qing-Xiao Tong and Jing-Xin Jian

Inorg. Chem., 2026, 65, 464
DOI: 10.1021/acs.inorgchem.5c04537

Constructing Co4(SO4)4 Clusters within Metal–Organic Frameworks for Efficient Oxygen Electrocatalysis

Zuozhong Liang, Guojun Zhou, Huang Tan, Yonghong Mou, Jieling Zhang, Hongbo Guo, Shujiao Yang, Haitao Lei, Haoquan Zheng, Wei Zhang, Haiping Lin and Rui Cao

Advanced Materials, 2024, 36
DOI: 10.1002/adma.202408094

Water oxidation activity of azo‐azomethine‐based Ni (II), Co (II), and Cu (II) complexes

Zohreh Shaghaghi, Parya Sallakh Kouhsangini and Rahim Mohammad‐Rezaei

Applied Organom Chemis, 2021, 35
DOI: 10.1002/aoc.6103

Water Oxidation by a Copper(II) Complex with 6,6′-Dihydroxy-2,2′-Bipyridine Ligand: Challenges and an Alternative Mechanism

Mohammad Saleh Ali Akbari, Subhajit Nandy, Keun Hwa Chae, Rahman Bikas, Anna Kozakiewicz-Piekarz and Mohammad Mahdi Najafpour

Langmuir, 2023, 39, 5542
DOI: 10.1021/acs.langmuir.3c00322

Bioinspired molecular clusters for water oxidation

Qi-Fa Chen, Yu-Hua Guo, Yi-Han Yu and Ming-Tian Zhang

Coordination Chemistry Reviews, 2021, 448, 214164
DOI: 10.1016/j.ccr.2021.214164

A Homogeneously Catalyzed Paired Electrolytic Cell for Hydrogen Peroxide Production

Caterina Trotta, Jesse Orta, Hendrik C. de Heer, Pim G. J. van Duren, Maxime A. Siegler, Gabriel Menendez Rodriguez, Alceo Macchioni and D. G. H. Hetterscheid

Angewandte Chemie, 2026
DOI: 10.1002/ange.202524811

Structure, magnetism and oxygen reduction reaction in mixed-valent Cu(I)⋯Cu(II) complex supported by benzimidazole derivative

Shi-Xiong Li, Jia-Wei Qiang and Bei-Ling Liao

Inorganica Chimica Acta, 2021, 521, 120356
DOI: 10.1016/j.ica.2021.120356

Design and Development of Sustainable Cu2 (II)- and Mn2 (III)-Embedded Bifunctional Electrocatalysts: Enhanced Hydrogen and Oxygen Generation

Niteesh Kumar, Lalita Wagh, Sajid Mehmood, Apurba K. Das and Tanmay Kumar Ghorai

Inorg. Chem., 2024, 63, 8567
DOI: 10.1021/acs.inorgchem.3c04271

Porphyrins, phthalocyanines, and related covalent-organic frameworks in the photochemical and electrochemical water splitting: A review

Oxana V. Kharissova, Yolanda Peña Méndez, Boris I. Kharisov, Aleksandr L. Nikolaev, Edith Luévano-Hipólito and Lucy T. González

Particuology, 2024, 90, 236
DOI: 10.1016/j.partic.2023.12.008

Pairing Oxygen Reduction and Water Oxidation for Dual‐Pathway H2O2 Production

Xin Sun, Jindi Yang, Xiangkang Zeng, Lijun Guo, Chuanbiao Bie, Zhuyuan Wang, Kaige Sun, Aloka Kumar Sahu, Mike Tebyetekerwa, Thomas E. Rufford and Xiwang Zhang

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202414417

Spin State Differentiated [3Fe–4S] Cluster Electrocatalyzes Water Oxidation Efficiently

Rong Yan, Qian‐Cheng Luo, Zi‐Han Li, Na‐Na Sun, Wei‐Peng Chen, Yuan‐Qi Zhai, Ho Johnny Chung Yin, Xiaotai Wang, Xin Tu and Yan‐Zhen Zheng

ChemSusChem, 2025, 18
DOI: 10.1002/cssc.202500812

Polydentate Adsorbent of Transition Metals Based on Hyperbranched Polyester Polyphthalate

Alina I. Vagapova, Aleksei F. Maksimov and Gennadiy A. Kutyrev

Russ J Gen Chem, 2025, 95, 3809
DOI: 10.1134/S1070363225604119

Backbone-controlled mechanistic switch in macrocyclic Cu(II) complexes: Directing oxygen evolution reaction pathways toward metal or ligand oxidation

Junyu Shen, Kaishan Yu, Liping Huang, Tao Wang, Yazi Liu, Wei Zhao and Jinxuan Liu

Journal of Colloid and Interface Science, 2026, 705, 139486
DOI: 10.1016/j.jcis.2025.139486

Theoretical Screening of the Water Oxidation Electrocatalytic Cycle Promoted by Single-Site Macrocyclic Copper(II) Complexes: Unraveling the Role of the HPO42– Anion under Neutral Conditions

João Pedro C. S. Neves, Joel Leitão Nascimento, Bruno S. Sampaio, Roberto Rivelino, Tiago Vinicius Alves and Vitor H. Menezes da Silva

ACS Org. Inorg. Au, 2026, 6, 53
DOI: 10.1021/acsorginorgau.5c00047

Water‐Soluble Polymers with Appending Porphyrins as Bioinspired Catalysts for the Hydrogen Evolution Reaction

Lisi Xie, Jia Tian, Yingjie Ouyang, Xinai Guo, Weian Zhang, Ulf‐Peter Apfel, Wei Zhang and Rui Cao

Angew Chem Int Ed, 2020, 59, 15844
DOI: 10.1002/anie.202003836

Synthesis of an Oxo-Bridged Fe(III) Porphyrin(2.1.2.1) Dimer and Its Enhanced Electrocatalytic Oxygen Evolution

Yuexin Wei, Yuanbo Zhou, Zuyu Zhang, Shihao Liu, Tao Ye, Xiaohui Zhao, Yue Wang, Ru Feng, Zhongti Sun, Nikolay V. Tkachenko, Fengxian Qiu, Hiroko Yamada and Songlin Xue

Inorg. Chem., 2025, 64, 22262
DOI: 10.1021/acs.inorgchem.5c04140

Strategic factors to design the next generation of molecular water oxidation catalysts: Lesson learned from ruthenium complexes

Abolfazl Ghaderian, Samrana Kazim, Mohammad Khaja Nazeeruddin and Shahzada Ahmad

Coordination Chemistry Reviews, 2022, 450, 214256
DOI: 10.1016/j.ccr.2021.214256

Electrocatalytic Water Oxidation by a Trinuclear Copper(II) Complex

Ana M. Geer, Charles Musgrave III, Christopher Webber, Robert J. Nielsen, Bradley A. McKeown, Chang Liu, P. Philipp M. Schleker, Peter Jakes, Xiaofan Jia, Diane A. Dickie, Josef Granwehr, Sen Zhang, Charles W. Machan, William A. Goddard and T. Brent Gunnoe

ACS Catal., 2021, 11, 7223
DOI: 10.1021/acscatal.1c01395

A Polymer-Derived Co(Fe)Ox Oxygen Evolution Catalyst Benefiting from the Oxidative Dehydrogenative Coupling of Cobalt Porphyrins

Drialys Cardenas-Morcoso, Deepak Bansal, Max Heiderscheid, Jean-Nicolas Audinot, Jérôme Guillot and Nicolas D. Boscher

ACS Catal., 2023, 13, 15182
DOI: 10.1021/acscatal.3c02940

Metal‐Corrole‐Based Porous Organic Polymers for Electrocatalytic Oxygen Reduction and Evolution Reactions

Haitao Lei, Qingxin Zhang, Zuozhong Liang, Hongbo Guo, Yabo Wang, Haoyuan Lv, Xialiang Li, Wei Zhang, Ulf‐Peter Apfel and Rui Cao

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202201104

Enhanced Photoelectrochemical Water Splitting of Black Silicon Photoanode with pH‐Dependent Copper‐Bipyridine Catalysts

Jing‐Xin Jian, Jia‐Xin Liao, Mu‐Han Zhou, Ming‐Ming Yao, Yi‐Jing Chen, Xi‐Wen Liang, Chao‐Ping Liu and Qing‐Xiao Tong

Chemistry A European J, 2022, 28
DOI: 10.1002/chem.202201520

Metalloporphyrins as Catalytic Models for Studying Hydrogen and Oxygen Evolution and Oxygen Reduction Reactions

Xialiang Li, Haitao Lei, Lisi Xie, Ni Wang, Wei Zhang and Rui Cao

Acc. Chem. Res., 2022, 55, 878
DOI: 10.1021/acs.accounts.1c00753

Earth-abundant nanomaterials for electrolytic hydrogen production: Advances, mechanistic insights, and industrial prospects

Govindhan Maduraiveeran, Palanisamy Kannan and Ali S. Alnaser

Renewable and Sustainable Energy Reviews, 2026, 231, 116750
DOI: 10.1016/j.rser.2026.116750

Excellent performance of water oxidation at low bias potential achieved by transparent WO3/BiVO4 photoanode integrated with molecular nickel porphyrin

Li Zhou, Yichu Wu, Lan Wang, Yulin Yang and Yong Na

Inorganic Chemistry Communications, 2019, 107, 107480
DOI: 10.1016/j.inoche.2019.107480

Redox Metal–Ligand Cooperativity Enables Robust and Efficient Water Oxidation Catalysis at Neutral pH with Macrocyclic Copper Complexes

Pablo Garrido-Barros, Dooshaye Moonshiram, Marcos Gil-Sepulcre, Primavera Pelosin, Carolina Gimbert-Suriñach, Jordi Benet-Buchholz and Antoni Llobet

J. Am. Chem. Soc., 2020, 142, 17434
DOI: 10.1021/jacs.0c06515

A Di-Copper-Peptoid in a Noninnocent Borate Buffer as a Fast Electrocatalyst for Homogeneous Water Oxidation with Low Overpotential

Guilin Ruan, Pritam Ghosh, Natalia Fridman and Galia Maayan

J. Am. Chem. Soc., 2021, 143, 10614
DOI: 10.1021/jacs.1c03225

Characterization of Reaction Intermediates Involved in the Water Oxidation Reaction of a Molecular Cobalt Complex

Moumita Bera, Simarjeet Kaur, Kritika Keshari, Dooshaye Moonshiram and Sayantan Paria

Inorg. Chem., 2022, 61, 21035
DOI: 10.1021/acs.inorgchem.2c03559

Homogeneous electrocatalytic water splitting by main group element porphyrins

Ni Wang, Yaochang Wang, Xin Liu, Ju Liu, Chenxiao Guo, Xing Deng, Jiangwei Liang, Minglei Cao and Ni Wang

International Journal of Hydrogen Energy, 2025, 177, 151412
DOI: 10.1016/j.ijhydene.2025.151412

Ligand Radical Mediated Water Oxidation by a Family of Copper o-Phenylene Bis-oxamidate Complexes

Samir Chattopadhyay, Arnab Ghatak, Youngju Ro, Régis Guillot, Zakaria Halime, Ally Aukauloo and Abhishek Dey

Inorg. Chem., 2021, 60, 9442
DOI: 10.1021/acs.inorgchem.1c00546

On the Mechanism of Heterogeneous Water Oxidation Catalysis: A Theoretical Perspective

Shanti Gopal Patra and Dan Meyerstein

Inorganics, 2022, 10, 182
DOI: 10.3390/inorganics10110182

Redox-active ligands in artificial photosynthesis: a review

Tímea Benkó, Dávid Lukács, Mingtao Li and József S. Pap

Environ Chem Lett, 2022, 20, 3657
DOI: 10.1007/s10311-022-01448-3

Molecular Mechanism of the Mononuclear Copper Complex‐Catalyzed Water Oxidation from Cluster‐Continuum Model Calculations

Peng Wu, Shengheng Yan, Wenhan Fang and Binju Wang

ChemSusChem, 2022, 15
DOI: 10.1002/cssc.202102508

Water‐Soluble Polymers with Appending Porphyrins as Bioinspired Catalysts for the Hydrogen Evolution Reaction

Lisi Xie, Jia Tian, Yingjie Ouyang, Xinai Guo, Weian Zhang, Ulf‐Peter Apfel, Wei Zhang and Rui Cao

Angewandte Chemie, 2020, 132, 15978
DOI: 10.1002/ange.202003836

First-row transition metal porphyrins for electrocatalytic hydrogen evolution — a SPP/JPP Young Investigator Award paper

Haitao Lei, Yabo Wang, Qingxin Zhang and Rui Cao

J. Porphyrins Phthalocyanines, 2020, 24, 1361
DOI: 10.1142/S1088424620500157

Advances in Electrocatalyzed Water Oxidation by Molecular Complexes of First Row Transition Metals

Chiara Lenzi, Andrea Masetti, Isacco Gualandi, Erika Scavetta, Luca Rigamonti and Rita Mazzoni

The Chemical Record, 2025, 25
DOI: 10.1002/tcr.202400266

Inactivation of antibiotic resistant bacterium Escherichia coli by electrochemical disinfection on molybdenum carbide electrode

Yinghan Liu, Shuai Zhang, Hao Fang, Qilin Wang, Shan Jiang, Chenxi Zhang and Pengxiang Qiu

Chemosphere, 2022, 287, 132398
DOI: 10.1016/j.chemosphere.2021.132398

Energy Landscape for the Electrocatalytic Oxidation of Water by a Single-Site Oxomanganese(V) Porphyrin

Dong Wang and John T. Groves

Inorg. Chem., 2022, 61, 13667
DOI: 10.1021/acs.inorgchem.2c02284

Exploring electron transfer: Bioinspired, biomimetics, and bioelectrochemical systems for sustainable energy and Value-Added compound synthesis

Graziela C. Sedenho, Rafael N. P. Colombo, Rodrigo M. Iost, Filipe C. D. A. Lima and Frank N. Crespilho

Applied Physics Reviews, 2024, 11
DOI: 10.1063/5.0204996

Water Oxidation at Neutral pH using a Highly Active Copper‐Based Electrocatalyst

Hussein A. Younus, Yan Zhang, Matthias Vandichel, Nazir Ahmad, Kari Laasonen, Francis Verpoort, Ce Zhang and Shiguo Zhang

ChemSusChem, 2020, 13, 5088
DOI: 10.1002/cssc.202001444

Electrocatalytic Hydrogen Evolution Using A Molecular Antimony Complex under Aqueous Conditions: An Experimental and Computational Study on Main‐Group Element Catalysis

Caroline K. Williams, Gavin A. McCarver, Ashwin Chaturvedi, Soumalya Sinha, Marcus Ang, Konstantinos D. Vogiatzis and Jianbing “Jimmy” Jiang

Chemistry A European J, 2022, 28
DOI: 10.1002/chem.202201323

Non‐Noble‐Metal‐Based Electrocatalysts for Acidic Oxygen Evolution Reaction: Recent Progress, Challenges, and Perspectives

Tingting Liu, Chen Chen, Zonghua Pu, Qiufeng Huang, Xiaofeng Zhang, Abdullah M. Al‐Enizi, Ayman Nafady, Shengyun Huang, Ding Chen and Shichun Mu

Small, 2024, 20
DOI: 10.1002/smll.202405399

A Dinuclear Copper Complex Featuring a Flexible Linker as Water Oxidation Catalyst with an Activity Far Superior to Its Mononuclear Counterpart

Xiongfei Zhang, Ying-Ying Li, Jian Jiang, Rong Zhang, Rong-Zhen Liao and Mei Wang

Inorg. Chem., 2020, 59, 5424
DOI: 10.1021/acs.inorgchem.9b03783

Recent Advances in Porphyrin-Based Systems for Electrochemical Oxygen Evolution Reaction

Bin Yao, Youzhou He, Song Wang, Hongfei Sun and Xingyan Liu

IJMS, 2022, 23, 6036
DOI: 10.3390/ijms23116036

Recent progress in production and usage of hydrogen peroxide

Shunichi Fukuzumi, Yong-Min Lee and Wonwoo Nam

Chinese Journal of Catalysis, 2021, 42, 1241
DOI: 10.1016/S1872-2067(20)63767-6

Unusual Water Oxidation Mechanism via a Redox-Active Copper Polypyridyl Complex

Daan den Boer, Andrey I. Konovalov, Maxime A. Siegler and Dennis G. H. Hetterscheid

Inorg. Chem., 2023, 62, 5303
DOI: 10.1021/acs.inorgchem.3c00477

Pairing Oxygen Reduction and Water Oxidation for Dual‐Pathway H2O2 Production

Xin Sun, Jindi Yang, Xiangkang Zeng, Lijun Guo, Chuanbiao Bie, Zhuyuan Wang, Kaige Sun, Aloka Kumar Sahu, Mike Tebyetekerwa, Thomas E. Rufford and Xiwang Zhang

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202414417

Synthetic strategies of single-atoms catalysts and applications in electrocatalysis

Jia Li, Mu-Fei Yue, Yi-Min Wei and Jian-Feng Li

Electrochimica Acta, 2022, 409, 139835
DOI: 10.1016/j.electacta.2022.139835