Magnetocaloric effect and slow magnetic relaxation in peroxide-assisted tetranuclear lanthanide assemblies

Pawan Kumar, Jessica Flores Gonzalez, Prem Prakash Sahu, Naushad Ahmed, Joydev Acharya, Vierandra Kumar, Olivier Cador, Fabrice Pointillart, Saurabh Kumar Singh and Vadapalli Chandrasekhar

Inorg. Chem. Front., 2022, 9, 5072
DOI: 10.1039/D2QI01260J

Recent advances in lanthanide coordination polymers and clusters with magnetocaloric effect or single-molecule magnet behavior

Jun-Jie Hu, Yan Peng, Sui-Jun Liu and He-Rui Wen

Dalton Trans., 2021, 50, 15473
DOI: 10.1039/D1DT02797B

A large magnetocaloric effect in two hybrid Gd-complexes: the synergy of inorganic and organic ligands towards excellent cryo-magnetic coolants

Jin-Hua Li, Ai-Ju Liu, Yu-Juan Ma, Song-De Han, Ji-Xiang Hu and Guo-Ming Wang

J. Mater. Chem. C, 2019, 7, 6352
DOI: 10.1039/C9TC01475F

Magnetic cooling: a molecular perspective

Piotr Konieczny, Wojciech Sas, Dominik Czernia, Aleksandra Pacanowska, Magdalena Fitta and Robert Pełka

Dalton Trans., 2022, 51, 12762
DOI: 10.1039/D2DT01565J

Gd(iii)-Based inorganic polymers, metal–organic frameworks and coordination polymers for magnetic refrigeration

Xiang Zhong, Jun-Jie Hu, Shu-Li Yao, Rui-Jie Zhang, Jin-Jin Wang, Ding-Gui Cai, Tong-Kai Luo, Yan Peng, Sui-Jun Liu and He-Rui Wen

CrystEngComm, 2022, 24, 2370
DOI: 10.1039/D1CE01633D

Development of magnetocaloric coordination polymers for low temperature cooling

Mario Falsaperna and Paul J. Saines

Dalton Trans., 2022, 51, 3394
DOI: 10.1039/D1DT04073A

A Gd-based borate–carbonate framework exhibiting a large magnetocaloric effect at a low magnetic field

Bo-Liang Liu, Qiao-Fei Xu, La-Sheng Long and Lan-Sun Zheng

Dalton Trans., 2021, 50, 12831
DOI: 10.1039/D1DT02624K

Two GdIII complexes with different structures and magnetocaloric properties induced by metal ion sources

Teng-Fei Zheng, Xue-Mei Tian, Lin-Hui Wu, Sui-Jun Liu, Shu-Li Yao, Kun-Huan He, Haiping Huang, Jinsheng Liao, Jing-Lin Chen and He-Rui Wen

New J. Chem., 2019, 43, 18445
DOI: 10.1039/C9NJ04984C

A new family of boat-shaped Ln8 clusters exhibiting the magnetocaloric effect and slow magnetic relaxation

Jia-Nian Li, Ning-Fang Li, Ji-Lei Wang, Xiao-Mei Liu, Qing-Dong Ping, Ting-Ting Zang, Hua Mei and Yan Xu

Dalton Trans., 2021, 50, 13925
DOI: 10.1039/D1DT02390J

Novel gadolinium garnet Gd3Te2Li3O12: magnetism and magnetocaloric performance for sub-kelvin cryogenic applications

Xuetong He, Lu Tian, Jianjian Gong, Xinqiang Gao, Guodong Liu and Zhaojun Mo

Dalton Trans., 2025, 54, 9739
DOI: 10.1039/D5DT00989H

Two Gd2 cluster complexes with monocarboxylate ligands displaying significant magnetic entropy changes

Teng-Fei Zheng, Xue-Mei Tian, Jie Ji, Hai Luo, Shu-Li Yao, Sui-Jun Liu, Bing-E Tang, Ya-Juan Zhao, Jiangang Mao, Qiang Zhao, Kun-Huan He and He-Rui Wen

Journal of Molecular Structure, 2020, 1200, 127094
DOI: 10.1016/j.molstruc.2019.127094

Direct measurement of magnetocaloric effect (MCE) in frustrated Gd-based molecular complexes

Yu Zhang, Tetsuya Nomoto, Satoshi Yamashita, Hiroki Akutsu, Nobuto Yoshinari, Takumi Konno and Yasuhiro Nakazawa

J Therm Anal Calorim, 2025, 150, 7179
DOI: 10.1007/s10973-024-13344-9

Synthesis, structure and magnetocaloric properties of a new two-dimensional gadolinium(III) coordination polymer based on azobenzene-2,2′,3,3′-tetracarboxylic acid

Wen-Wen Wei, Li-Ping Lu, Si-Si Feng, Miao-Li Zhu and Ulli Englert

Acta Crystallogr C Struct Chem, 2021, 77, 591
DOI: 10.1107/S2053229621008871

Large magnetic entropy change in weberite-type oxides Gd3MO7 (M = Nb, Sb, and Ta)

Ziyu Yang, Shijun Qin, Xubin Ye, Zhehong Liu, Yujie Guo, Hongzhi Cui, Jun-Yi Ge, Hui Li, Youwen Long and Yu-Jia Zeng

Sci. China Phys. Mech. Astron., 2022, 65
DOI: 10.1007/s11433-021-1834-4

Large Magnetocaloric Effect in Li3K9Gd3(BO3)7 Crystal Featuring Sandwich-Like Three-Dimensional Framework

Wang Liu, Fei Liang, Yuwei Chen, Huimin Song, Jingcheng Feng, Jun Shen, Zheshuai Lin, Heng Tu and Guochun Zhang

Inorg. Chem., 2021, 60, 6796
DOI: 10.1021/acs.inorgchem.1c00633

Magnetocaloric Effect and Thermal Conductivity of a 3D Coordination Polymer of [Gd(HCOO)(C2O4)]n

Qiao-Fei Xu, Bo-Liang Liu, Ming-Yu Ye, La-Sheng Long and Lan-Sun Zheng

Inorg. Chem., 2021, 60, 9259
DOI: 10.1021/acs.inorgchem.1c01152

Lanthanide Contraction in Action: Structural Variations in 13 Lanthanide(III) Thiophene-2,5-dicarboxylate Coordination Polymers (Ln = La–Lu, Except Pm and Tm) Featuring Magnetocaloric Effect, Slow Magnetic Relaxation, and Luminescence-Lifetime-based Thermometry

Manesh Kumar, Le-Qian Li, Jan K. Zaręba, Lobzang Tashi, Subash Chandra Sahoo, Marcin Nyk, Sui-Jun Liu and Haq Nawaz Sheikh

Crystal Growth & Design, 2020, 20, 6430
DOI: 10.1021/acs.cgd.0c00611

NaGdS2: A Promising Sulfide for Cryogenic Magnetic Cooling

Charlène Delacotte, Tatiana A. Pomelova, Thomas Stephant, Thierry Guizouarn, Stéphane Cordier, Nikolay G. Naumov and Pierric Lemoine

Chem. Mater., 2022, 34, 1829
DOI: 10.1021/acs.chemmater.1c04105

A cryogenic magnetic refrigerant: Magnetocaloric study of EuB2O4 compound

Yuanpeng Wang, Quanyi Liu, Lu Tian, Zhihong Hao, Lei Zhang, Qi Fu, Jinliang Zhao and Zhaojun Mo

Journal of Alloys and Compounds, 2024, 995, 174753
DOI: 10.1016/j.jallcom.2024.174753

Two dinuclear GdIII clusters based on isobutyric acid and nicotinic acid with large magnetocaloric effects

Min Zhou, Lin-Hui Wu, Xin-Yu Wu, Shu-Li Yao, Teng-Fei Zheng, Xin Xie and Sui-Jun Liu

Journal of Molecular Structure, 2021, 1227, 129689
DOI: 10.1016/j.molstruc.2020.129689

Magnetocaloric and barocaloric effects of metal complexes for solid state cooling: Review, trends and perspectives

Mario S. Reis

Coordination Chemistry Reviews, 2020, 417, 213357
DOI: 10.1016/j.ccr.2020.213357

Gadolinium-Rich Borate Gd17.33(BO3)4(B2O5)2O16 Exhibiting a Magnetocaloric Effect

Huimin Song, Naizheng Wang, Wang Liu, Jingcheng Feng, Jun Shen, Wei Dai, Zheshuai Lin, Jiyong Yao and Guochun Zhang

Inorg. Chem., 2020, 59, 11071
DOI: 10.1021/acs.inorgchem.0c01547

In-situ synthesis of molecular magnetorefrigerant materials

Sui-Jun Liu, Song-De Han, Jiong-Peng Zhao, Jialiang Xu and Xian-He Bu

Coordination Chemistry Reviews, 2019, 394, 39
DOI: 10.1016/j.ccr.2019.05.009

Magnetocaloric properties of Gd2MoO6 prepared by a simple and fast method

V. Tkáč, E. Tothová, K. Tibenská, A. Orendáčová, M. Orendáč and R. Tarasenko

Ceramics International, 2021, 47, 24421
DOI: 10.1016/j.ceramint.2021.05.157

Sr14.06Gd14.63(BO3)24: A Gadolinium-Rich Borate with Magnetic Refrigeration Performance

Yuwei Chen, Wang Liu, Dong Wang, Naizheng Wang, Feidi Fan, Jun Shen, Guochun Zhang, Huimin Song and Heng Tu

Inorg. Chem., 2023, 62, 10263
DOI: 10.1021/acs.inorgchem.3c01060

Large cryogenic magnetocaloric effect in Na5Gd4F(SiO4)4

Zuhua Chen, Shilin Yu, Guochun Zhang, Changkun Wang, Jiahao Gao, Yicai Zhang, Yanan Zhao, Zhenxing Li, Jun Shen and Heng Tu

Cryogenics, 2024, 143, 103955
DOI: 10.1016/j.cryogenics.2024.103955

Enhancing the performance of magnetic refrigerants through tuning their magnetism from antiferromagnetism to weak ferromagnetism

Qiaofei Xu, Boliang Liu, Han Xu, Mingyu Ye, Lasheng Long and Lansun Zheng

Sci. China Mater., 2022, 65, 3171
DOI: 10.1007/s40843-022-2109-9

Investigation of Gd(III) 2D Metal–Organic Frameworks for Magnetic Refrigeration

Dipanti Borah, Nareshwararajan B. Sankarammal, Himani Goyal, Sanjog S. Nagarkar and Maheswaran Shanmugam

Inorg. Chem., 2025, 64, 14651
DOI: 10.1021/acs.inorgchem.5c02306

Achieving Magnetic Refrigerants with Large Magnetic Entropy Changes and Low Magnetic Ordering Temperatures

Qiao-Fei Xu, Man-Ting Chen, Ruo-Tong Wu, La-Sheng Long and Lan-Sun Zheng

J. Am. Chem. Soc., 2024, 146, 20116
DOI: 10.1021/jacs.4c04258

Recent advance in heterometallic nanomagnets based on TMxLn4−x cubane subunits

Jin Wang, Min Feng, Muhammad Nadeem Akhtar and Ming-Liang Tong

Coordination Chemistry Reviews, 2019, 387, 129
DOI: 10.1016/j.ccr.2019.02.008

Strong Magnetocaloric Coupling in Oxyorthosilicate with Dense Gd3+ Spins

Ziyu W. Yang, Jie Zhang, Dabiao Lu, Xiaoxiao Zhang, Haoting Zhao, Hongzhi Cui, Yu-Jia Zeng and Youwen Long

Inorg. Chem., 2023, 62, 5282
DOI: 10.1021/acs.inorgchem.3c00421

Improvement on Magnetocaloric Effect through Structural Evolution in Gadolinium Borate Halides Ba2Gd(BO3)2X (X = F, Cl)

Yuwei Chen, Pifu Gong, Ruixin Guo, Feidi Fan, Jun Shen, Guochun Zhang and Heng Tu

Inorg. Chem., 2023, 62, 15584
DOI: 10.1021/acs.inorgchem.3c02139

Large magnetocaloric effect in Gd2Si2O7 and plateau-like magnetic entropy change in Dy2Si2O7

Lei Wang, Zhongwen Ouyang, Zhengrong Li, Jiaojiao Cao and Zhengcai Xia

Journal of Alloys and Compounds, 2023, 969, 172402
DOI: 10.1016/j.jallcom.2023.172402

Achievement of table-like magnetocaloric effect and enhanced refrigerant capacity in the dual-phase Ho5Pd2/Ho3Pd2 composite

Xiaofei Wu, Yusong Du, Xinqiang Gao, Fei Liu, Lei Ma, Gang Cheng, Jiang Wang, Jingtai Zhao and Guanghui Rao

Journal of Alloys and Compounds, 2025, 1010, 177742
DOI: 10.1016/j.jallcom.2024.177742

Principles for Creating “Molecular Refrigerators” Derived from Gadolinium(III) Coordination Compounds: A Review

A. V. Pavlishchuk and V. V. Pavlishchuk

Theor Exp Chem, 2020, 56, 1
DOI: 10.1007/s11237-020-09635-5

Large magnetocaloric effect in gadolinium-rich silicate NaGd9(SiO4)6O2

Zuhua Chen, Chengliang Zhang, Zhengming Zhang, Shilin Yu, Guochun Zhang, Heng Tu, Dunhui Wang and Jun Shen

Journal of Alloys and Compounds, 2024, 976, 173351
DOI: 10.1016/j.jallcom.2023.173351

Construction of the Lanthanide Diphosphonates via a Template-Synthesis Strategy: Structures, Proton Conduction, and Magnetic Behavior

Jie Pan, Yu-Juan Ma, Song-De Han, Ji-Xiang Hu, Ying Mu and Guo-Ming Wang

Crystal Growth & Design, 2019, 19, 3045
DOI: 10.1021/acs.cgd.9b00293