Issue 18, 2022

A mild and efficient oxidative degradation system of epoxy thermosets: full recovery and degradation mechanism

Abstract

Despite its high energy efficiency, the oxidative degradation of thermosetting resins has some limitations in practical application due to the complexity and non-selectivity of the oxidation reaction. Here, ammonium ceric nitrate (CAN) aqueous solution was used as the oxidative system to achieve complete and controllable degradation of amine cured epoxy resin (EP) and a 99% degradation rate could be achieved in 1 h at 60 °C. Exploration of the mechanism revealed that the hydroxyethyl ether unit had an important role in the degradation, and degradation products with a high molecular weight (Mw > 8000) were obtained. The resin and CAN can be recycled and reutilised as adhesives, and a high-efficiency catalyst, respectively. In particular, commercial carbon fibre reinforced epoxy resin composite (CFRP) can also be recycled by this degradation system, with the acquisition of nearly non-destructive fibres and resin degradation products that can also be used for bonding.

Graphical abstract: A mild and efficient oxidative degradation system of epoxy thermosets: full recovery and degradation mechanism

Supplementary files

Article information

Article type
Paper
Submitted
05 মে 2022
Accepted
27 জুন 2022
First published
31 আগ. 2022

Green Chem., 2022,24, 7082-7091

A mild and efficient oxidative degradation system of epoxy thermosets: full recovery and degradation mechanism

Y. Long, F. Tian, L. Bai, W. An, X. Zhao, R. Du, X. Liu, X. Zhou, S. Xu and Y. Wang, Green Chem., 2022, 24, 7082 DOI: 10.1039/D2GC01678H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements