Issue 11, 2018

Carbon nanodots in ZIF-8: synthesis, tunable luminescence and temperature sensing

Abstract

A new hybrid material, CNDs@ZIF-8, has been synthesized by the calcination of ZIF-8 nanocrystals. Carbon nanodots (CNDs) are produced from the decomposition of organic ligands such as 2-methylimidazole, which are embedded in the interrupted cavities in the framework during calcination. The resultant CNDs@ZIF-8 composites not only possess the intact structure of ZIF-8, but also have slightly enhanced adsorption ability and higher BET surface area compared to ZIF-8. Moreover, hybrid material CNDs@ZIF-8 exhibit tunable luminescence resulting from the inherent blue emission of ZIF-8 and the yellow emission of CNDs with different intensities controlled by the calcination time. The CNDs@ZIF-8 composites can also be used as temperature sensors. This work paves a feasible way for the development of CNDs@MOF materials with both luminescence and adsorption properties.

Graphical abstract: Carbon nanodots in ZIF-8: synthesis, tunable luminescence and temperature sensing

Supplementary files

Article information

Article type
Research Article
Submitted
03 জুলাই 2018
Accepted
29 জুলাই 2018
First published
30 জুলাই 2018

Inorg. Chem. Front., 2018,5, 2739-2745

Carbon nanodots in ZIF-8: synthesis, tunable luminescence and temperature sensing

Y. Wang, B. Wang, H. Shi, C. Zhang, C. Tao and J. Li, Inorg. Chem. Front., 2018, 5, 2739 DOI: 10.1039/C8QI00637G

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