Multicomponent self-sorting of a Pd7 molecular boat and its use in catalytic Knoevenagel condensation

Dipak Samanta; Partha Sarathi Mukherjee

doi:10.1039/C2CC37377G

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Multicomponent self-sorting of a Pd₇ molecular boat and its use in catalytic Knoevenagel condensation†‡

Dipak Samanta^a and Partha Sarathi Mukherjee*^a

Author affiliations

* Corresponding authors

^a Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560 012, India
E-mail: psm@ipc.iisc.ernet.in
Fax: +91-80-2360-1552
Tel: +91-80-2293-3352

Abstract

Unique three-component self-assembly of a cis-blocked 90° Pd(II) acceptor with a mixture of tri- and tetra-imidazole donors led to the self-sorting of a Pd₇ molecular boat with an internal nanocavity, which catalyses the Knoevenagel condensation of a series of aromatic aldehydes with 1,3-dimethylbarbituric acid and Meldrum's acid in aqueous media.

This article is part of the themed collection: Emerging Investigators 2013

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C2CC37377G
Article type: Communication
Submitted: 09 অক্টো. 2012
Accepted: 17 ডিসে. 2012
First published: 18 ডিসে. 2012

Download Citation

Chem. Commun., 2013,49, 4307-4309

Permissions

Request permissions

Multicomponent self-sorting of a Pd₇ molecular boat and its use in catalytic Knoevenagel condensation

D. Samanta and P. S. Mukherjee, Chem. Commun., 2013, 49, 4307 DOI: 10.1039/C2CC37377G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications