Issue 39, 2013

Reactions of a tungsten–germylyne complex with alcohols and arylaldehydes

Abstract

A germylyne complex Cp*(CO)2W[triple bond, length as m-dash]GeC(SiMe3)3 (1) reacted with alcohols to give simple nucleophilic addition products, while 1 reacted with two molecules of arylaldehydes consecutively to give base-stabilised alkoxy(germylene) complexes via C–H bond activation and hydrogermylation.

Graphical abstract: Reactions of a tungsten–germylyne complex with alcohols and arylaldehydes

Supplementary files

Article information

Article type
Communication
Submitted
01 অক্টো. 2012
Accepted
01 নভে. 2012
First published
02 নভে. 2012

Chem. Commun., 2013,49, 4232-4234

Reactions of a tungsten–germylyne complex with alcohols and arylaldehydes

T. Fukuda, H. Hashimoto and H. Tobita, Chem. Commun., 2013, 49, 4232 DOI: 10.1039/C2CC37126J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements