Exploring the effect of pressure on the crystal structure and caloric properties of the molecular ionic hybrid [(CH3)3NOH]2[CoCl4]†
Pedro
Dafonte-Rodríguez, 
‡a
Ignacio
Delgado-Ferreiro,
‡a
Javier
García-Ben,
a
Angel
Ferradanes-Martínez,
a
María
Gelpi,
a
Julian
Walker,
b
Charles James
McMonagle,
c
Socorro
Castro-García,
a
María Antonia
Señarís-Rodríguez,
a
Juan Manuel
Bermúdez-García
*a
and
Manuel
Sánchez-Andújar
*a
‡a
Ignacio
Delgado-Ferreiro,
‡a
Javier
García-Ben,
a
Angel
Ferradanes-Martínez,
a
María
Gelpi,
a
Julian
Walker,
b
Charles James
McMonagle,
c
Socorro
Castro-García,
a
María Antonia
Señarís-Rodríguez,
a
Juan Manuel
Bermúdez-García
*a
and
Manuel
Sánchez-Andújar
*a
Abstract
The hybrid metal halide [(CH3)3NOH]2CoCl4 exhibits a first-order phase transition at T ∼ 343 K. Its crystal structure and caloric properties respond significantly to moderate pressures (1–1000 bar), demonstrating potential for applications in emerging solid-state refrigeration technologies.
![Graphical abstract: Exploring the effect of pressure on the crystal structure and caloric properties of the molecular ionic hybrid [(CH3)3NOH]2[CoCl4]](/bn/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=D4CC05125D&imageInfo.ImageIdentifier.Year=2024)
- This article is part of the themed collection: Chemistry for a Sustainable World – Celebrating Our Community Tackling Global Challenges
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