N-Heterocyclic carbene-stabilised arsinidene (AsH)†
Manfred
Scheer 
*b
and
Matthias
Tamm
*a
*b
and
Matthias
Tamm
*a
Abstract
N-Heterocyclic carbene adducts of the parent arsinidene (AsH) were prepared by two different synthetic routes, either by reaction of As(SiMe3)3 with 2,2-difluoroimidazolines followed by desilylation or by reaction of [Na(dioxane)3.31][AsCO] with imidazolium chlorides.
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