Zn0.999Ni0.001S photocatalysts (energy gap = 2.3 eV) heat-treated at 773 K in an N2 flow showed activity for hydrogen evolution from aqueous solutions containing K2SO3 and Na2S as reducing reagents under visible light irradiation without co-catalysts such as Pt.
Photocatalytic H2 evolution under visible light irradiation on Ni-doped ZnS photocatalyst
A. Kudo and M. Sekizawa, Chem. Commun., 2000, 1371 DOI: 10.1039/B003297M
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