Li-Lin Jiang, Hui Qiu, Yu Zhou, Ling-Tao Wang, Wen-Hui Yang, Chao Deng and Wen-Ting Wei
Org. Chem. Front., 2023,10, 6096-6102
From themed collection:
2023 Organic Chemistry Frontiers HOT articles
Abstract
We describe a novel 1,2,2-trifunctionalization of maleimides with 1,7-enynes and oxime esters through simultaneous construction of four C−C bonds and a C≡N bond in one pot based on the radical relay/1,5-hydrogen-atom transfer (HAT).
Jingyi Wang, Yuchan Wang, Jibin Li, Zexuan Wei, Jie Feng and Ding Du
Chem. Commun., 2023,59, 5395-5398
Abstract
The first N-heterocyclic carbene organocatalytic three-component radical relay trifunctionalization of unactivated alkenes through the combination of remote 1,4-cyano migration and alkylacylation was reported.
Fushan Chen, Zhu Cao and Chen Zhu
Chem. Commun., 2024,60, 14912-14923
From themed collection:
Chemical Communications HOT Articles 2024
Abstract
This feature article summarizes our achievements in radical-mediated intramolecular functional group migration reactions, aiming to provide a comprehensive understanding of the progress in this emerging area.
Shaobo Ren, Jian Zhu and Yunkui Liu
Org. Biomol. Chem., 2024,22, 5982-5986
Abstract
The NCS/AgNO2 system enables an unprecedented trifunctionalization of C![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
C bonds in vinyl azides to access densely functionalized phenanthridines in a one-pot manner.
Xiong Yang, Jinmin Luo, Ji Li, Yao Yuan and Gangguo Zhu
Org. Chem. Front., 2025,12, 5333-5339
Abstract
A BPO triggered 1,2,3-trifunctionalization of α,α-disubstituted vinyl aldehydes enabled by radical 1,2-formyl migration is developed, providing a number of trifluoromethylated alkynyl aldehydes under mild conditions.