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Zhanfeng Wang, Xiaodi Fu, Wenwen Diao, Yao Wu, Carme Rovira and Binju Wang

Chem. Sci., 2025, 16, 3173
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Copper–oxygen adducts: new trends in characterization and properties towards C–H activation

Jonathan De Tovar, Rébecca Leblay, Yongxing Wang, Laurianne Wojcik, Aurore Thibon-Pourret, Marius Réglier, A. Jalila Simaan, Nicolas Le Poul and Catherine Belle

Chem. Sci., 2024, 15, 10308
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The mechanism behind the oxidase activity of cellulose-active AA10 lytic polysaccharide monooxygenases

Erna K. Wieduwilt, Marlisa M. Hagemann, Ulf Ryde and Erik D. Hedegård

Inorg. Chem. Front., 2025, 12, 5344
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pH-mediated manipulation of the histidine brace in LPMOs and generation of a tri-anionic variant, investigated by EPR, ENDOR, ESEEM and HYSCORE spectroscopy

Julia Haak, Ole Golten, Morten Sørlie, Vincent G. H. Eijsink and George E. Cutsail

Chem. Sci., 2025, 16, 233
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Metal-mediated peptide processing. How copper and iron catalyze diverse peptide modifications such as amidation and crosslinking

Ninian J. Blackburn

RSC Chem. Biol., 2025, 6, 1048
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The rotamer of the second-sphere histidine in AA9 lytic polysaccharide monooxygenase is pH dependent

Ingvild Isaksen, Suvamay Jana, Christina M. Payne, Bastien Bissaro and Åsmund K. Røhr

Biophysical Journal, 2024, 123, 1139
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C-H Activation with Cu(I) MOFs: The Pertinence of Natural-Like Active Centres and Their Facile Modification

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The General Atomic and Molecular Electronic Structure System (GAMESS): Novel Methods on Novel Architectures

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J. Chem. Theory Comput., 2023, 19, 7031
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Revealing the atomic and electronic mechanism of human manganese superoxide dismutase product inhibition

Jahaun Azadmanesh, Katelyn Slobodnik, Lucas R. Struble, William E. Lutz, Leighton Coates, Kevin L. Weiss, Dean A. A. Myles, Thomas Kroll and Gloria E. O. Borgstahl

Nat Commun, 2024, 15
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Perdeuterated GbpA Enables Neutron Scattering Experiments of a Lytic Polysaccharide Monooxygenase

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ACS Omega, 2023, 8, 29101
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On the pH Dependency of the Catalysis by a Lytic Polysaccharide Monooxygenase from the Fungus Trichoderma reesei

Silja Kuusk, Maarja Lipp, Surabhi Mahajan and Priit Väljamäe

ACS Catal., 2024, 14, 13408
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Second-Sphere Histidine Catalytic Function in a Fungal Polysaccharide Monooxygenase

Allison E. Batka, William C. Thomas, Dan A. Tudorica, Richard I. Sayler and Michael A. Marletta

Biochemistry, 2024, 63, 3136
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Joint X-ray/neutron structure of Lentinus similis AA9_A at room temperature

Tobias Tandrup, Leila Lo Leggio and Flora Meilleur

Acta Crystallogr F Struct Biol Commun, 2023, 79, 1
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Current insights of factors interfering the stability of lytic polysaccharide monooxygenases

Meiling Dan, Yuting Zheng, Guohua Zhao, Yves S.Y. Hsieh and Damao Wang

Biotechnology Advances, 2023, 67, 108216
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A Conserved Second Sphere Residue Tunes Copper Site Reactivity in Lytic Polysaccharide Monooxygenases

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J. Am. Chem. Soc., 2023, 145, 18888
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Expanding the catalytic landscape of metalloenzymes with lytic polysaccharide monooxygenases

Alessia Munzone, Vincent G. H. Eijsink, Jean-Guy Berrin and Bastien Bissaro

Nat Rev Chem, 2024, 8, 106
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Computation of Protein–Ligand Binding Free Energies with a Quantum Mechanics-Based Mining Minima Algorithm

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J. Chem. Theory Comput., 2025, 21, 4236
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Capturing the Binuclear Copper State of Peptidylglycine Monooxygenase Using a Peptidyl-Homocysteine Lure

Katherine W. Rush, Karsten A. S. Eastman, Evan F. Welch, Vahe Bandarian and Ninian J. Blackburn

J. Am. Chem. Soc., 2024, 146, 5074
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Insight into the peroxygenase activity of lytic polysaccharide monooxygenases (LPMO): Recent progress and mechanistic understanding

Wa Gao and Heng Yin

Chemical Physics Reviews, 2023, 4
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The upsurge of lytic polysaccharide monooxygenases in biomass deconstruction: characteristic functions and sustainable applications

Asheesh Kumar, Aishwarya Singh, Vijay Kumar Sharma, Akshita Goel and Arun Kumar

The FEBS Journal, 2024, 291, 5081
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Investigating the Substrate Oxidation Mechanism in Lytic Polysaccharide Monooxygenase: H2O2- versus O2-Activation

Marlisa M. Hagemann, Erna K. Wieduwilt, Ulf Ryde and Erik D. Hedegård

Inorg. Chem., 2024, 63, 21929
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Engineering a Functional Histidine Brace Copper-Binding Site into a De Novo-Designed Protein Scaffold

Salvatore La Gatta, Linda Leone, Gianmattia Sgueglia, Lorena Šimunić, Yu-Kai Liao, Ondřej Vaněk, Marco Chino, Flavia Nastri, Mario Chiesa and Angela Lombardi

JACS Au, 2025, 5, 4799
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Mechanism of Oxidative C─H Bond Activation by De Novo Designed Artificial Cu Metalloenzymes Using H2O2 and O2

Divyansh Prakash, Yao Wu, Sandeep K. Misra, Nishanthini Sampath, Binju Wang and Saumen Chakraborty

Chemistry A European J, 2025, 31
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Assessing the role of redox partners in TthLPMO9G and its mutants: focus on H2O2 production and interaction with cellulose

Koar Chorozian, Anthi Karnaouri, Nefeli Georgaki-Kondyli, Antonis Karantonis and Evangelos Topakas

Biotechnol Biofuels, 2024, 17
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Mimicking the Reactivity of LPMOs with a Mononuclear Cu Complex

Kundan Sagar, Michael Kim, Tong Wu, Shuming Zhang, Emile L. Bominaar, Maxime A. Siegler, Michael Hendrich and Isaac Garcia‐Bosch

Eur J Inorg Chem, 2024, 27
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Revisiting enzyme engineering strategies and reaction mechanisms of lytic polysaccharide monooxygenases (LPMOs)

Musaddique Hossain, Shalini Das, Subba Reddy Dodda, Kamalpreet Singh, Tiyasa Bhuniya, Tiasha Ghosh and Sudit S. Mukhopadhyay

Critical Reviews in Biotechnology, 2026, 46, 460
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Copper(II)-Oxyl Formation in a Biomimetic Complex Activated by Hydrogen Peroxide: The Key Role of Trans-Bis(Hydroxo) Species

Ning Cao, Abril C. Castro, David Balcells, Unni Olsbye and Ainara Nova

Inorg. Chem., 2024, 63, 23082
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Electron transfer in polysaccharide monooxygenase catalysis

Richard I. Sayler, William C. Thomas, Alexander J. Rose and Michael A. Marletta

Proc. Natl. Acad. Sci. U.S.A., 2025, 122
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High-Valent Late Transition Metal-Oxo Complexes: Breaking Boundaries at the Oxo Wall and Beyond

Nabhendu Pal, Nicole A. Fritsch, Jason Shearer and Nicolai Lehnert

Chem. Rev., 2026
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Chitin-active lytic polysaccharide monooxygenases and its synergistic effect with chitinases

Anbang Li, Kecheng Li, Ronge Xing and Song Liu

Bioresource Technology, 2025, 436, 133022
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Impact of the Copper Second Coordination Sphere on Catalytic Performance and Substrate Specificity of a Bacterial Lytic Polysaccharide Monooxygenase

Kelsi R. Hall, Maja Mollatt, Zarah Forsberg, Ole Golten, Lorenz Schwaiger, Roland Ludwig, Iván Ayuso-Fernández, Vincent G. H. Eijsink and Morten Sørlie

ACS Omega, 2024, 9, 23040
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A designed Copper Histidine-brace enzyme for oxidative depolymerization of polysaccharides as a model of lytic polysaccharide monooxygenase

Yiwei Liu, Kevin A. Harnden, Casey Van Stappen, Sergei A. Dikanov and Yi Lu

Proc. Natl. Acad. Sci. U.S.A., 2023, 120
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A Four-Coordinate End-On Superoxocopper(II) Complex: Probing the Link between Coordination Number and Reactivity

Suman Debnath, Shoba Laxmi, Olivia McCubbin Stepanic, Sebastian Y. Quek, Maurice van Gastel, Serena DeBeer, Tobias Krämer and Jason England

J. Am. Chem. Soc., 2024, 146, 23704
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