Electrocatalysis as an enabling technology for organic synthesis

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Chem. Soc. Rev., 2021, 50, 7941
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Renewable electron-driven bioinorganic nitrogen fixation: a superior route toward green ammonia?

Bo Wang, Yifeng Zhang and Shelley D. Minteer

Energy Environ. Sci., 2023, 16, 404
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Direct bioelectrocatalysis by redox enzymes immobilized in electrostatically condensed oppositely charged polyelectrolyte electrode coatings

Koun Lim, Monika Sima, Russell J. Stewart and Shelley D. Minteer

Analyst, 2020, 145, 1250
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A biocompatible hydrogel as a template for oxidative decomposition reactions: a chemodosimetric analysis and in vitro imaging of hypochlorite

Dipen Biswakarma, Nilanjan Dey and Santanu Bhattacharya

Chem. Sci., 2022, 13, 2286
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Structure, dynamics, and redox reactivity of an all-purpose flavodoxin

Sharique Khan, Ahmadullah Ansari, Monica Brachi, Debarati Das, Wassim El Housseini, Shelley Minteer and Anne-Frances Miller

Journal of Biological Chemistry, 2024, 300, 107122
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Natural and Engineered Electron Transfer of Nitrogenase

Wenyu Gu and Ross D. Milton

Chemistry, 2020, 2, 322
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Fundamentals, Applications, and Future Directions of Bioelectrocatalysis

Hui Chen, Olja Simoska, Koun Lim, Matteo Grattieri, Mengwei Yuan, Fangyuan Dong, Yoo Seok Lee, Kevin Beaver, Samali Weliwatte, Erin M. Gaffney and Shelley D. Minteer

Chem. Rev., 2020, 120, 12903
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Electron Transfer in Nitrogenase

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Chem. Rev., 2020, 120, 5158
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Design of a Peroxidase‐Based Gas Diffusion Electrode for Bioelectroenzymatic Applications

Vladyslav Mishyn, Nunzio Giorgio G. Carducci, David P. Hickey and Sofiene Abdellaoui

Electroanalysis, 2025, 37
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Conductive Polymers and Their Nanocomposites: Application Features in Biosensors and Biofuel Cells

Lyubov S. Kuznetsova, Vyacheslav A. Arlyapov, Yulia V. Plekhanova, Sergei E. Tarasov, Anna S. Kharkova, Evgeniya A. Saverina and Anatoly N. Reshetilov

Polymers, 2023, 15, 3783
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Mild polarization electric field in ultra-thin BN-Fe-graphene sandwich structure for efficient nitrogen reduction

Ziyuan Xiu, Wei Mu, Xin Zhou and Xiaojun Han

Chinese Journal of Catalysis, 2024, 65, 126
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Detection of Acetaminophen in Groundwater by Laccase-Based Amperometric Biosensors Using MoS2 Modified Carbon Paper Electrodes

Marcela Herrera-Domínguez, Koun Lim, Iris Aguilar-Hernández, Alejandra García-García, Shelley D. Minteer, Nancy Ornelas-Soto and Raúl Garcia-Morales

Sensors, 2023, 23, 4633
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Insights from Enzymatic Catalysis: A Path towards Bioinspired High‐Performance Electrocatalysts

Graziela C. Sedenho, Rafael N. P. Colombo and Frank N. Crespilho

ChemCatChem, 2023, 15
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Bioelectrochemical conversion of carbon dioxide into hydrocarbons and other sustainable renewable fuels

Kumarasamy Jayakumar, Huangxian Ju, Simonas Ramanavicius and Arunas Ramanavicius

Fuel, 2026, 408, 137335
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An engineered, non-diazotrophic cyanobacterium and its application in bioelectrochemical nitrogen fixation

Fangyuan Dong, Yoo Seok Lee, Erin M. Gaffney, Matteo Grattieri, Helena Haddadin, Shelley D. Minteer and Hui Chen

Cell Reports Physical Science, 2021, 2, 100444
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The versatility of pyrene and its derivatives on sp2 carbon nanomaterials for bioelectrochemical applications

Michael Holzinger, Serge Cosnier and Paulo Henrique M. Buzzetti

Synthetic Metals, 2023, 292, 117219
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Bioelectrocatalytic Refining of Lignin Fragments Using a Bioinspired β-Etherolytic Bioanode

Vladyslav Mishyn, Layal Abdallah, Nunzio Giorgio G. Carducci, Juliette Floret, David P. Hickey and Sofiene Abdellaoui

ACS Catal., 2023, 13, 16258
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Rapid Entrapment of Phenazine Ethosulfate within a Polyelectrolyte Complex on Electrodes for Efficient NAD+ Regeneration in Mediated NAD+-Dependent Bioelectrocatalysis

Koun Lim, Yoo Seok Lee, Olja Simoska, Fangyuan Dong, Monika Sima, Russell J. Stewart and Shelley D. Minteer

ACS Appl. Mater. Interfaces, 2021, 13, 10942
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Artificial, Photoinduced Activation of Nitrogenase Using Directed and Mediated Electron Transfer Processes

Matan M. Meirovich, Oren Bachar and Omer Yehezkeli

Catalysts, 2020, 10, 979
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Light-driven, bias-free nitrogenase-based bioelectrochemical cell for ammonia generation

Matan M. Meirovich, Oren Bachar, Mor Shemesh, Yifat Cohen, Alice Popik and Omer Yehezkeli

Biosensors and Bioelectronics, 2024, 255, 116254
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Sustainable media feedstocks for cellular agriculture

Lutz Grossmann

Biotechnology Advances, 2024, 73, 108367
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Insights into Nitrogenase Bioelectrocatalysis for Green Ammonia Production

Trevor D. Rapson, Christina M. Gregg, Robert S. Allen, HyungKuk Ju, Cara M. Doherty, Xavier Mulet, Sarbjit Giddey and Craig C. Wood

ChemSusChem, 2020, 13, 4856
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Molecular mechanisms of electron transfer employed by native proteins and biological-inorganic hybrid systems

Michael Lienemann

Computational and Structural Biotechnology Journal, 2021, 19, 206
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Assembly of an improved hybrid cascade system for complete ethylene glycol oxidation: Enhanced catalytic performance for an enzymatic biofuel cell

Jefferson Honorio Franco, João Victor Bonaldo, Shelley D. Minteer and Adalgisa R. De Andrade

Biosensors and Bioelectronics, 2022, 216, 114649
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Emerging electrocatalysts for green ammonia production: Recent progress and future outlook

Sajid Mahmood, Shahid Iqbal, Zeping Wang, Muhammad Ammar, Muhammad Javed Iqbal, Ali Bahadur, Nasser S. Awwad and Hala A. Ibrahium

Arabian Journal of Chemistry, 2024, 17, 105950
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Enzyme Electrochemistry for Industrial Energy Applications—A Perspective on Future Areas of Focus

John C. Ruth and Alfred M. Spormann

ACS Catal., 2021, 11, 5951
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Nitrogenase Bioelectrochemistry for Synthesis Applications

Ross D. Milton and Shelley D. Minteer

Acc. Chem. Res., 2019, 52, 3351
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Bioelectrocatalytic Synthesis: Concepts and Applications

Dylan G. Boucher, Emily Carroll, Zachary A. Nguyen, Rohit G. Jadhav, Olja Simoska, Kevin Beaver and Shelley D. Minteer

Angewandte Chemie, 2023, 135
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Electroenzymatic N2 reduction to ammonia by nitrogenase from Azotobacter vinelandii immobilized on low density graphite electrodes under direct electron transfer regime

Gabriel García-Molina, Carlos Echavarri-Erasun, Melisa del Barrio, Sandra González-García, Luis M. Rubio, Marcos Pita and Antonio L. De Lacey

Electrochimica Acta, 2025, 529, 146342
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Step Towards Enzymatic Bioelectrorefinery: Design of a Ligninolytic Hybrid Air‐Breathing Biocathode

Vladyslav Mishyn, Juliette Floret, Brigitte Chabbert, Véronique Aguié‐Béghin, David Crônier, Nunzio Giorgio G. Carducci, David P. Hickey and Sofiene Abdellaoui

ChemCatChem, 2025, 17
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Establishing a Thermodynamic Landscape for the Active Site of Mo-Dependent Nitrogenase

David P. Hickey, Rong Cai, Zhi-Yong Yang, Katharina Grunau, Oliver Einsle, Lance C. Seefeldt and Shelley D. Minteer

J. Am. Chem. Soc., 2019, 141, 17150
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Review on biomaterial applications of photoresponsive based chromophore Hydrogels: Recent developments and future perspectives

Mani Rajasekar, Venugopal Kavyashree, Elango Sangamithra, Pavithra Baskaran, Michelle Faustina Maria, Jennita Mary, Meenamigai Sivakumar and Masilamani Selvam

Results in Chemistry, 2024, 7, 101462
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Recent Enzymatic Electrochemistry for Reductive Reactions

Cécile Cadoux and Ross D. Milton

ChemElectroChem, 2020, 7, 1974
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Advanced Electroanalysis for Electrosynthesis

Monica Brachi, Wassim El Housseini, Kevin Beaver, Rohit Jadhav, Ashwini Dantanarayana, Dylan G. Boucher and Shelley D. Minteer

ACS Org. Inorg. Au, 2024, 4, 141
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Electroenzymatic Nitrogen Fixation Using a MoFe Protein System Immobilized in an Organic Redox Polymer

Yoo Seok Lee, Adrian Ruff, Rong Cai, Koun Lim, Wolfgang Schuhmann and Shelley D. Minteer

Angew Chem Int Ed, 2020, 59, 16511
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Pyrene‐Based Noncovalent Immobilization of Nitrogenase on Carbon Surfaces

Janki Patel, Rong Cai, Ross Milton, Hui Chen and Shelley D. Minteer

ChemBioChem, 2020, 21, 1729
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Templating Porphyrin Anisotropy via Magnetically Aligned Carbon Nanotubes

Luka Đorđević, Tomas Marangoni, Mingjie Liu, Rita De Zorzi, Silvano Geremia, Andrea Minoia, Roberto Lazzaroni, Yasuhiro Ishida and Davide Bonifazi

ChemPlusChem, 2019, 84, 1270
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Intracellular dark-field imaging of ATP and photothermal therapy using a colorimetric assay based on gold nanoparticle aggregation via tetrazine/trans-cyclooctene cycloaddition

Fei Liu, Yingshu Guo, Yinhua Hu, Xiaoru Zhang and Xiangjiang Zheng

Anal Bioanal Chem, 2019, 411, 5845
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A Multifunctional Electrochemical Biosensor Based on Near-Infrared Light-Responsive Hydrogel for In Vivo Recording and Modulation

Congyu Zhang, Qi Zheng, Cui Li, Yue Zhu, Jiaqi Ji, Guang Yang, Changman Guo, Yiwei Wang, Qing Zhu, Weizhong Zhu, Dingyi Fu and Shushu Ding

Anal. Chem., 2025, 97, 12164
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Elektroenzymatische Stickstofffixierung unter Verwendung eines MoFe‐Proteinsystems immobilisiert in einem organischen Redoxpolymer

Yoo Seok Lee, Adrian Ruff, Rong Cai, Koun Lim, Wolfgang Schuhmann and Shelley D. Minteer

Angewandte Chemie, 2020, 132, 16654
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The Structure of Bilirubin Oxidase from Bacillus pumilus Reveals a Unique Disulfide Bond for Site-Specific Direct Electron Transfer

Shalev Gihaz, Nidaa Shrara Herzallh, Yifat Cohen, Oren Bachar, Ayelet Fishman and Omer Yehezkeli

Biosensors, 2022, 12, 258
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Bioelectrocatalytic Synthesis: Concepts and Applications

Dylan G. Boucher, Emily Carroll, Zachary A. Nguyen, Rohit G. Jadhav, Olja Simoska, Kevin Beaver and Shelley D. Minteer

Angew Chem Int Ed, 2023, 62
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Enzymatic Bioreactors: An Electrochemical Perspective

Simin Arshi, Mehran Nozari-Asbemarz and Edmond Magner

Catalysts, 2020, 10, 1232
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Hydrogen sustainability pathways: Advanced hydrogen carriers and emerging production routes

Shikha Dahiya, P. Chiranjeevi, Narnepati Krishna Chaitanya, Shashidhar Thatikonda and Gurjit Singh Bharara

Bioresource Technology Reports, 2026, 102753
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Artificial Enzymatic Electrochemistry

Nya E. Black, Dara Cheng, Brandon P. Grasty and Dylan G. Boucher

ChemElectroChem, 2025, 12
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The progress and outlook of bioelectrocatalysis for the production of chemicals, fuels and materials

Hui Chen, Fangyuan Dong and Shelley D. Minteer

Nat Catal, 2020, 3, 225
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Advancements in Bioelectrocatalysis for Electrochemical Ammonia Production: Integrating Enzyme‐Based Catalysis

Kumarasamy Jayakumar, Dharmalingam Sakthilatha and Raja Venkatesan

ChemistrySelect, 2025, 10
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One-Pot Bioelectrocatalytic Conversion of Chemically Inert Hydrocarbons to Imines

Hui Chen, Tianhua Tang, Christian A. Malapit, Yoo Seok Lee, Matthew B. Prater, N. Samali Weliwatte and Shelley D. Minteer

J. Am. Chem. Soc., 2022, 144, 4047
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Analysis of the Ammonia Production Rates by Nitrogenase

Trevor D. Rapson and Craig C. Wood

Catalysts, 2022, 12, 844
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A voltammetric study of nitrogenase MoFe-protein using low-potential electron transfer mediators

Artavazd Badalyan, Zhi-Yong Yang and Lance C. Seefeldt

Bioelectrochemistry, 2024, 155, 108575
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Cytochrome P450 3A4 electrochemical sensor for testing testosterone metabolism: modulation by luteolin and relevance for food-drug interactions

Carina S.P. Vieira, Sara Cravo, Emília Sousa, Marcela A. Segundo and Alberto N. Araújo

Electrochimica Acta, 2025, 540, 147201
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Nitrogenase Bioelectrocatalysis: From Understanding Electron-Transfer Mechanisms to Energy Applications

Rong Cai and Shelley D. Minteer

ACS Energy Lett., 2018, 3, 2736
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Electrochemical Characterization of Isolated Nitrogenase Cofactors from Azotobacter vinelandii

Brian R. Lydon, Chi Chung Lee, Kazuki Tanifuji, Nathaniel S. Sickerman, Megan P. Newcomb, Yilin Hu, Markus W. Ribbe and Jenny Y. Yang

ChemBioChem, 2020, 21, 1773
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From Enzyme Stability to Enzymatic Bioelectrode Stabilization Processes

Charlène Beaufils, Hiu-Mun Man, Anne de Poulpiquet, Ievgen Mazurenko and Elisabeth Lojou

Catalysts, 2021, 11, 497
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Defining Intermediates of Nitrogenase MoFe Protein during N2 Reduction under Photochemical Electron Delivery from CdS Quantum Dots

Bryant Chica, Jesse Ruzicka, Hayden Kallas, David W. Mulder, Katherine A. Brown, John W. Peters, Lance C. Seefeldt, Gordana Dukovic and Paul W. King

J. Am. Chem. Soc., 2020, 142, 14324
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Information Transmission through Biotic–Abiotic Interfaces to Restore or Enhance Human Function

Alexander R. Kelly and Dominic J. Glover

ACS Appl. Bio Mater., 2024, 7, 3605
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Recent Advances and Challenges of Electrocatalytic N2Reduction to Ammonia

Geletu Qing, Reza Ghazfar, Shane T. Jackowski, Faezeh Habibzadeh, Mona Maleka Ashtiani, Chuan-Pin Chen, Milton R. Smith and Thomas W. Hamann

Chem. Rev., 2020, 120, 5437
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Tailoring Quantum Dot Sizes for Optimal Photoinduced Catalytic Activation of Nitrogenase

Matan M. Meirovich, Oren Bachar, Ramesh Nandi, Nadav Amdursky and Omer Yehezkeli

ChemSusChem, 2021, 14, 5410
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Bioelectrocatalysis for synthetic applications: Utilities and challenges

Kevin M. McFadden, Luke G. Kays, Dylan G. Boucher and Shelley D. Minteer

Current Opinion in Electrochemistry, 2024, 44, 101458
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Breath biosensing: using electrochemical enzymatic sensors for detection of biomarkers in human breath

Erin M. Gaffney, Koun Lim and Shelley D. Minteer

Current Opinion in Electrochemistry, 2020, 23, 26
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Strategies for Bioelectrochemical CO2 Reduction

Mengwei Yuan, Matthew J. Kummer and Shelley D. Minteer

Chemistry A European J, 2019, 25, 14258
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Upgraded Bioelectrocatalytic N2 Fixation: From N2 to Chiral Amine Intermediates

Hui Chen, Rong Cai, Janki Patel, Fangyuan Dong, Hsiaonung Chen and Shelley D. Minteer

J. Am. Chem. Soc., 2019, 141, 4963
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Enzymatic electrosynthesis as an emerging electrochemical synthesis platform

Ranran Wu, Chunling Ma and Zhiguang Zhu

Current Opinion in Electrochemistry, 2020, 19, 1
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Light-Driven Fe3O4–Azotobacter vinelandii Biohybrids for Enhanced Nitrogen Fixation

Meng Jiang, Yujie Wang, Guangyu Liu, Hao Yuan, Jiangyuan Pan, Wei Xiong, Yilei Guo, Chao Gao, Tingting Kong and Yujie Xiong

ACS Materials Lett., 2026, 8, 966
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Photoelectrocatalytic‐Microbial Biohybrid for Nitrogen Reduction

Yingjie Zhang, Tianhang Feng, Xue Zhou and Zhonghai Zhang

Advanced Materials, 2024, 36
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Perfluorocarbon nanoemulsions create a beneficial O2 microenvironment in N2-fixing biological | inorganic hybrid

Shengtao Lu, Roselyn M. Rodrigues, Shuyuan Huang, Daniel A. Estabrook, John O. Chapman, Xun Guan, Ellen M. Sletten and Chong Liu

Chem Catalysis, 2021, 1, 704
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Interfacing nature’s catalytic machinery with synthetic materials for semi-artificial photosynthesis

Nikolay Kornienko, Jenny Z. Zhang, Kelsey K. Sakimoto, Peidong Yang and Erwin Reisner

Nature Nanotech, 2018, 13, 890
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Enzymatic Bioelectrocatalysis for Enzymology Applications

Matthew J. Kummer and Shelley D. Minteer

ChemElectroChem, 2020, 7, 2222
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The Journey toward Low Temperature, Low Pressure Catalytic Nitrogen Fixation

Run Shi, Xuerui Zhang, Geoffrey I. N. Waterhouse, Yunxuan Zhao and Tierui Zhang

Advanced Energy Materials, 2020, 10
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Fe‐VS2 Electrocatalyst with Organic Matrix‐Mediated Electron Transfer for Highly Efficient Nitrogen Fixation

Ziyuan Xiu, Ming Zheng, Jiadong Li, Feng Wei, Changchang Dong, Mingrui Zhang, Xin Zhou and Xiaojun Han

ChemSusChem, 2022, 15
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