Synthesis, characterization, X-ray and electronic structures of diethyl ether and 1,2-dimethoxyethane adducts of molybdenum(iv) chloride and tungsten(iv) chloride

Thomas E. Shaw, Timothy J. Diethrich, Charlotte L. Stern, Brian L. Scott, Titel Jurca, Thomas M. Gilbert and Alfred P. Sattelberger

Dalton Trans., 2022, 51, 7856
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Insights into group 4 and 5 ansa-bis(cyclopentadienyl) complexes with a single-atom bridge

Sanjiv Prashar, Antonio Antiñolo and Antonio Otero

Coordination Chemistry Reviews, 2006, 250, 133
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Niobium, titanium, zirconium and hafnium complexes incorporating germanium bridged ansa ligands. X-Ray crystal structures of [Zr{Me2Ge(η5-C5Me4)2}Cl2] and [M{Me2Ge(η5-C5Me4)(η5-C5H4)}Cl2] (M=Zr, Hf)

Carlos Alonso-Moreno, Antonio Antiñolo, Isabel López-Solera, Antonio Otero, Sanjiv Prashar, Ana M Rodrı́guez and Elena Villaseñor

Journal of Organometallic Chemistry, 2002, 656, 129
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Synthesis, hydrosilylation reactivity and catalytic properties of group 4 ansa-metallocene complexes

Santiago Gómez-Ruiz, Sanjiv Prashar, Mariano Fajardo, Antonio Antiñolo, Antonio Otero, Miguel A. Maestro, Victoria Volkis, Moris S. Eisen and César J. Pastor

Polyhedron, 2005, 24, 1298
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Transition Metal Polyhydrides: From Qualitative Ideas to Reliable Computational Studies

Feliu Maseras, Agustí Lledós, Eric Clot and Odile Eisenstein

Chem. Rev., 2000, 100, 601
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Photoinduced FeCp Bond Cleavage and Insertion Reactions of Strained Silicon‐ and Sulphur‐Bridged [1]Ferrocenophanes in the Presence of Transition‐Metal Carbonyls

Nga Sze Ieong, Wing Yan Chan, Alan J. Lough, Mairi F. Haddow and Ian Manners

Chemistry A European J, 2008, 14, 1253
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Structure and Dynamics of a Dihydrogen/Hydride Ansa Molybdenocene Complex

Vincent Pons, Stephen L. J. Conway, Malcolm L. H. Green, Jennifer C. Green, Benjamin J. Herbert and D. Michael Heinekey

Inorg. Chem., 2004, 43, 3475
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Hydrosilylation in the Design and Functionalization of ansa-Metallocene Complexes

Antonio Antiñolo, Mariano Fajardo, Santiago Gómez-Ruiz, Isabel López-Solera, Antonio Otero and Sanjiv Prashar

Organometallics, 2004, 23, 4062
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New Group 4 Metallocene and Niobocene Complexes Containing Phosphane-Functionalizedansa-Ligands

Antonio Antiñolo, Rafael Fernández-Galán, Irache Orive, Antonio Otero and Sanjiv Prashar

Eur. J. Inorg. Chem., 2002, 2002, 2470
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Group 4 metallocene complexes incorporating vinyl or allyl substituted ansa ligands. X-Ray crystal structures of [Zr{Me(CH2CH)Si(η5-C5Me4)2}Cl2], [Zr{Me(CH2CHCH2)Si(η5-C5H4)2}Cl2] and [Zr{Me(CH2CHCH2)Si(η5-C5Me4)(η5-C5H4)}Cl2]

Antonio Antiñolo, Mariano Fajardo, Santiago Gómez-Ruiz, Isabel López-Solera, Antonio Otero, Sanjiv Prashar and Ana M Rodrı́guez

Journal of Organometallic Chemistry, 2003, 683, 11
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Reactivity of Zirconium Complexes Incorporating Asymmetrically Substituted ansa Ligands and Their Use as Catalysts in Olefin Polymerization. X-ray Crystal Structures of [Me2Si(η5-C5Me4)(η5-C5H3R)]ZrCl2 (R = Et, iPr)

Antonio Antiñolo, Isabel López-Solera, Antonio Otero, Sanjiv Prashar, Ana M. Rodríguez and Elena Villaseñor

Organometallics, 2002, 21, 2460
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Bridging-terminal exchange in ansa-bridged tetrahydroborate niobocene compounds: a density functional study

Nicholas J Ashworth, Stephen L.J Conway, Jennifer C Green and Malcolm L.H Green

Journal of Organometallic Chemistry, 2000, 609, 83
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Synthesis and characterization of [W(NC4Me4)2Cl2] and [W(NC4Me4)2(CH3)2], the first azametallocene tungsten complexes with pyrrolyl ligands. Electronic structure and bonding of tungsten bispyrrolyl complexes

José R Ascenso, Alberto R Dias, André P Ferreira, Ana Castro Galvão, Margarida S Salema and Luis F Veiros

Inorganica Chimica Acta, 2003, 356, 249
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Gespannte Metallocenophane und ähnliche metallorganische Ringe mit π‐Kohlenwasserstoffliganden und Übergangsmetallzentren

David E. Herbert, Ulrich F. J. Mayer and Ian Manners

Angewandte Chemie, 2007, 119, 5152
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Hydrogen/deuterium exchange in alkyl-hydride derivatives of ansa-tungstenocene compounds

Malcolm L.H. Green, Stephen L.J. Conway and Linda H. Doerrer

Polyhedron, 2005, 24, 1388
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A Study on Zr–Ir Multiple Bonding Active for C–H Bond Cleavage

Masataka Oishi, Masato Oshima and Hiroharu Suzuki

Inorg. Chem., 2014, 53, 6634
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Synthesis and electrochemistry of niobium complexes incorporating asymmetrically substituted ansa-ligands

Antonio Antiñolo, Teresa Expósito, Isabel del Hierro, Dominique Lucas, Yves Mugnier, Irache Orive, Antonio Otero and Sanjiv Prashar

Journal of Organometallic Chemistry, 2002, 655, 63
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Synthesis and Reactivity of Alkylzirconium Complexes Incorporating Asymmetrically Substituted ansa Ligands − X‐ray Crystal Structure of [Zr{Me2Si(η5‐C5Me4)(η5‐C5H3Me)}(CH2Ph)Cl]

Antonio Antiñolo, Rafael Fernández‐Galán, Beatriz Gallego, Antonio Otero, Sanjiv Prashar and Ana M. Rodríguez

Eur J Inorg Chem, 2003, 2003, 2626
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Strained Metallocenophanes and Related Organometallic Rings Containing π‐Hydrocarbon Ligands and Transition‐Metal Centers

David E. Herbert, Ulrich F. J. Mayer and Ian Manners

Angew Chem Int Ed, 2007, 46, 5060
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ansa-Chromocene Complexes. 1. Synthesis and Characterization of Cr(II) Carbonyl andtert-Butyl Isocyanide Complexes

Gilbert J. Matare, David M. Foo, Kevin M. Kane, Ralph Zehnder, Marion Wagener, Pamela J. Shapiro, Tom Concolino and Arnold L. Rheingold

Organometallics, 2000, 19, 1534
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Niobium and Zirconium Complexes Incorporating Asymmetrically Substituted ansa Ligands. X-ray Crystal Structures of [Me2Si(η5-C5Me4)(η5-C5H3R)]Nb(NtBu)Cl (R = Me, iPr) and [Me2Si(η5-C5Me4)(η5-C5H3R)]ZrCl2 (R = H, Me)

Antonio Antiñolo, Isabel López-Solera, Irache Orive, Antonio Otero, Sanjiv Prashar, Ana M. Rodríguez and Elena Villaseñor

Organometallics, 2001, 20, 71
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Structure–reactivity correlations in new W(IV) and Nb(IV) silicon-bridged ansa-metallocene hydrides

Stephen L.J. Conway, Malcolm L.H. Green, Sofia I. Pascu and Henry O. Peake

Polyhedron, 2006, 25, 406
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Silicon–Carbon bond cleavage reactions of Ansa tungstenocene compounds: The [Me 2 Si] bridge as a site for metallocene functionalization

Cary E. Zachmanoglou, Hyosun Lee, Seung Ho Jang, Keliang Pang and Gerard Parkin

Proc. Natl. Acad. Sci. U.S.A., 2008, 105, 11060
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Theoretical Study of the Oxidative Addition of 16-Electron d4 [n]-Metallocenophane Complexes with Methane

Ming-Der Su and San-Yan Chu

J. Phys. Chem. A, 2001, 105, 3591
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Organometallic chemistry in aqueous solution: Reactions catalyzed by water-soluble molybdocenes

Kerry L. Breno, Takiya J. Ahmed, Michael D. Pluth, Christoph Balzarek and David R. Tyler

Coordination Chemistry Reviews, 2006, 250, 1141
DOI: 10.1016/j.ccr.2005.12.001