Rb3B5O8F2 and K0.6Rb2.4B5O8F2: two new deep-ultraviolet transparent nonlinear optical fluorooxoborates designed by cation regulation

Ruonan Zhang; Bingliang Cheng; Xuping Wang; Rong Yang; Zhihua Yang; Shujuan Han; Shilie Pan

doi:10.1039/D2QI01466A

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Rb₃B₅O₈F₂ and K_0.6Rb_2.4B₅O₈F₂: two new deep-ultraviolet transparent nonlinear optical fluorooxoborates designed by cation regulation†

Ruonan Zhang,‡^ab Bingliang Cheng,‡^ab Xuping Wang,

^a Rong Yang,^ab Zhihua Yang,

^a Shujuan Han

*^a and Shilie Pan

*^a

Author affiliations

* Corresponding authors

^a Research Center for Crystal Materials; CAS Key Laboratory of Functional Materials and Devices for Special Environments; Xinjiang Technical Institute of Physics and Chemistry, CAS, 40-1 South Beijing Road, Urumqi 830011, China
E-mail: hansj@ms.xjb.ac.cn, slpan@ms.xjb.ac.cn

^b Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

Two new fluorooxoborates, Rb₃B₅O₈F₂ and K_0.6Rb_2.4B₅O₈F₂, were successfully obtained by cation regulation. Both of them crystallize in a non-centrosymmetric space group P2₁. The structural evolution from Li₂Na_0.9K_0.1B₅O₈F₂ to Rb₃B₅O₈F₂, as well as the structural comparison between RbB₅O₈ and Rb₃B₅O₈F₂, is discussed in detail. The linear optical and nonlinear optical properties were measured. Furthermore, the structure–property relationships of the alkali metal fluorooxoborates were determined by theoretical calculations.

This article is part of the themed collections: 2023 Inorganic Chemistry Frontiers HOT articles and FOCUS: Frontiers in Boron Chemistry

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/D2QI01466A
Article type: Research Article
Submitted: 08 юли 2022
Accepted: 05 дек 2022
First published: 07 дек 2022

Download Citation

Inorg. Chem. Front., 2023,10, 787-792

Permissions

Request permissions

Rb₃B₅O₈F₂ and K_0.6Rb_2.4B₅O₈F₂: two new deep-ultraviolet transparent nonlinear optical fluorooxoborates designed by cation regulation

R. Zhang, B. Cheng, X. Wang, R. Yang, Z. Yang, S. Han and S. Pan, Inorg. Chem. Front., 2023, 10, 787 DOI: 10.1039/D2QI01466A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Inorganic Chemistry Frontiers